1998
DOI: 10.3891/acta.chem.scand.52-0067
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The SRN1 Reaction: An Attempt to Calculate the Thermodynamic Driving Force for the Addition of Nucleophiles to Phenyl Radical.

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Cited by 19 publications
(38 citation statements)
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“…The corresponding values from the aromatic homologues (i.e., PhϪY) are given in parentheses. [22] [d] From kcal/mol for Ph · , [30] and the reasonable agreement with these data supports the reliability of our semiempirical calculations. In combination with the ∆H°f value of H · (52.1 kcal/ mol), [31] the data in Table 4 enable the involved BDE CϪH values to be calculated.…”
Section: Semiempirical Calculationssupporting
confidence: 81%
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“…The corresponding values from the aromatic homologues (i.e., PhϪY) are given in parentheses. [22] [d] From kcal/mol for Ph · , [30] and the reasonable agreement with these data supports the reliability of our semiempirical calculations. In combination with the ∆H°f value of H · (52.1 kcal/ mol), [31] the data in Table 4 enable the involved BDE CϪH values to be calculated.…”
Section: Semiempirical Calculationssupporting
confidence: 81%
“…[12] This confirms that aryl radicals are both thermodynamically and kinetically efficient in their reaction with the enolate ions, with rate constants approaching the diffusion limit (ca. 10 11  Ϫ1 ·s Ϫ1 ) [22] in these solvents.…”
Section: Competition Between Nucleophilic Attack and H-atom Abstractimentioning
confidence: 88%
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