The solubilities of two representative potassium carboxylate salts at 25 °C in the aqueous cyclic ethers, 1,4-dioxane and tetrahydrofuran, and their relationship to mean solvent polarity

McNaney, John A.; Zimmerman, Fr. Michael; Zimmerman, Howard K.

doi:10.1007/bf00798642

Cited by 4 publications

(8 citation statements)

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“…The values of parameters Ai in Eqs. (2) and 3, together with those given in [16] for Eq. (1), are reported in Table 3; the temperature range of validity of each equation is also indicated, except for Eq.…”

Section: -A Temperature Dependent Correlation For the Relative Permimentioning

confidence: 99%

“…where T0 = 298.15K and (2) LK  =0, except for interactions between the group H2O and groups OH of alcohols (Table 7c). Table 1.…”

Section: Appendix B Group Contribution Parameter Estimationmentioning

confidence: 99%

“…8. VLE of methanol (1) -water (2) with: (a) NaCl at T=396K for ms=0 ( ), ms=2.76 ( ), ms=4.84 ( ), (b) KCl at P=1.01bar for m=0.5 ( ), m=1 ( ), m=2 ( ), (c) LiCl at P=1.01bar for m=1 ( , ), m=2 ( , ), m=4 ( , ), (d) NaBr at T=313K for ms=1 ( ), ms=2 ( ), ms=4 ( ). Calculation with the NRTL-PRA EoS (─).…”

Section: Table 7cmentioning

confidence: 99%

“…9. VLE of ethanol (1) -water (2) Table 3 Parameter values of the literature correlations for relative permittivity, together with their temperature range of validity. NR: Eq.…”

Section: Table 7cmentioning

confidence: 99%

“…solubility of the solute [1] and therefore it can be used to predict this property by means of theoretical equations [1,2] or empirical correlations [3,4]. Consequently, equations for relative permittivity are of great interest for chemical engineering processes.…”

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An empirical correlation for the relative permittivity of liquids in a wide temperature range: Application to the modeling of electrolyte systems with a GE/EoS approach

Raspo

Neau

2020

Fluid Phase Equilibria

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Relative permittivity, also known as static dielectric constant, is a key property of solvents in electrolyte solutions. It strongly influences the solubility of solutes and, therefore, it can be used as a predictive tool in chemical engineering processes. Relative permittivity also plays an essential role in the modeling of phase equilibria of electrolyte systems, since it is involved in the Debye-Hückel model and in the Mean Spherical Approximation, commonly used to represent long-range interactions between ions. In this paper, we propose a new temperature-dependent correlation for the relative permittivity of liquid water, methanol and ethanol, valid in a wide temperature range, including very high temperatures. Comparison with other literature equations evidenced that the main interest of the proposed correlation is to allow satisfactory predictions of the relative permittivity, not only in the range of validity of other literature models, but also in the high temperature domain, including supercritical temperatures for water. The new correlation is then used with the NRTL-PRA EoS to predict vapor pressure of water with several salts, including single electrolytes and two-salts mixtures; it must be noted that the modeling presented in this work is relevant for any G E /EoS model, since in this case (binary interactions between water and ions being equal to zero), the excess Gibbs energy reduces to the Long-Range term derived from the Pitzer-Debye-Hückel model. A temperaturedependent correction of the solvent relative permittivity is proposed to account for its dependence on ion mole fraction in this Long-Range term. Results thus obtained show that this correction leads to an accurate prediction both: for vapor pressures of aqueous electrolyte solutions in a very wide temperature domain and for the modeling of vapor-liquid equilibria of methanol-water and ethanolwater mixtures with several salts.

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Section: -A Temperature Dependent Correlation For the Relative Permimentioning

confidence: 99%

“…where T0 = 298.15K and (2) LK  =0, except for interactions between the group H2O and groups OH of alcohols (Table 7c). Table 1.…”

Section: Appendix B Group Contribution Parameter Estimationmentioning

confidence: 99%

Section: Table 7cmentioning

confidence: 99%

“…9. VLE of ethanol (1) -water (2) Table 3 Parameter values of the literature correlations for relative permittivity, together with their temperature range of validity. NR: Eq.…”

Section: Table 7cmentioning

confidence: 99%

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