The Sharpless Asymmetric Aminohydroxylation—Scope and Limitation

Abstract

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Studies toward the Synthesis of Chartelline C

“…Since macrolactam 14a was obtained from 13 as a single diastereomer, our approach is expected to be applicable to the synthesis of enantioenriched chartelline C, which could be synthesized from enantioenriched 9, prepared by the asymmetric aminohydroxylation of alkene 5. 17,18 Studies toward the asymmetric synthesis of chartelline C via this approach are ongoing in our laboratory.…”