The Sermons of M. John Calvin upon the Fifth Book of Moses called Deuteronomy

Calvin, John

doi:10.2307/j.ctt1p5f238.12

Cited by 12 publications

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“…Unlike the Class I compounds, 10 is just as air-stable as α-Co(salen). This led Calvin to describe pyridine and piperidine (pip) as “blocking agents” due to their ability to prevent O 2 sorption . The crystal structure of 10 (SALECI) showing the axially coordinated pyridine was reported in 1970 .…”

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confidence: 99%

“…Powder patterns of the phases originating from activation of Co(3F-salen)pip·(H 2 O) to form the O 2 active γ-Co(3F-salen), oxygenation to give γ-Co(3F-salen)(O 2 ) 1/2 , or deactivation to δ-Co(3F-salen) ( 19 ), red line = calculated powder pattern and teal sticks = powder data reported by Calvin (top). A description of how these data were translated into the teal sticks can be found in the Supporting Information (Tables S3 and S4).…”

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confidence: 99%

“…The realization that this potentially highly useful function was accessible for a synthetic compound and importantly in the solid state paved the way for proposing practical energy-saving swing absorption technologies for separating molecular oxygen from air. This goal motivated the U.S. National Defense Research Committee sponsored work by Calvin who described the reactivity of 57 cobalt(II) complexes in the solid state toward O 2 , including 42 salen-derived complexes, in two patents, , a book, and a series of articles published after World War II. − Intriguingly, out of this extensive study, occasionally on the kilogram scale, only Co(salen) and Co(3F-salen) (3F-salen = N , N′ -ethylene-bis(3-flourosalicylideneiminato)) were ultimately patented by Calvin, ,, suggesting that these complexes were deemed the most active. Since this seminal work, the Co(salen) scaffold has been studied extensively in numerous modifications incorporating, e.g.…”

Section: Introductionmentioning

confidence: 99%

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Structure Activity Relationships for Reversible O₂ Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Møller

McKenzie

2023

JACS Au

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The potential of solid-state materials comprising Co(salen) units for concentrating dioxygen from air was recognized over 80 years ago. While the chemisorptive mechanism at the molecular level is largely understood, the bulk crystalline phase plays important, yet unidentified roles. We have reverse crystal-engineered these materials and can for the first time describe the nanostructuring requisite for achieving reversible O2 chemisorption by Co(3R-salen) R = H or F, the simplest and most effective of the many known derivatives of Co(salen). Of the six phases of Co(salen) identified, α-ζ: α = ESACIO, β = VEXLIU, γ, δ, ε, and ζ (this work), only γ, δ, ε, and ζ are capable of reversible O2 binding. Class I materials (phases γ, δ, and ε) are obtained by desorption (40–80 °C, atmospheric pressure) of the co-crystallized solvent from Co(salen)·(solv), solv = CHCl3, CH2Cl2, or 1.5 C6H6. The oxy forms comprise between 1:5 and 1:3 O2:[Co] stoichiometries. Class II materials achieve an apparent maximum of 1:2 O2:Co(salen) stoichiometries. The precursors for the Class II materials comprise [Co(3R-salen)(L)·(H2O) x ], R = H, L = pyridine, and x = 0; R = F, L = H2O, and x = 0; R = F, L = pyridine, and x = 0; R = F, L = piperidine, and x = 1. Activation of these depends on the desorption of the apical ligand (L) that templates channels through the crystalline compounds with the Co(3R-salen) molecules interlocked in a Flemish bond brick pattern. The 3F-salen system produces F-lined channels proposed to facilitate O2 transport through the materials through repulsive interactions with the guest O2. We postulate that a moisture dependence of the activity of the Co(3F-salen) series is due to a highly specific binding pocket for locking in water via bifurcated hydrogen bonding to the two coordinated phenolato O atoms and the two ortho F atoms.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Structure Activity Relationships for Reversible O₂ Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Møller

McKenzie

2023

JACS Au

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“…9 At other points, he argued that a 'sacrament is nothing else than a visible word or sculpture and image of the grace of God'. 10 Similarly, and on a vastly larger scale, Randall Zachman compellingly argues in Image and Word in the Theology of John Calvin that manifestation and proclamation go hand in hand for Calvin, where far more attention needs to be paid to Calvin's profound emphasis upon the multiple ways God chooses to be manifested. He catalogs a plethora of examples of Calvin's positive approach to images in his theology, noting their profound and consistent attachment to God's Word.…”

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Calvin's Visual Exegesis of Old Testament Prophecy: Figural Reading and the Sacramental Character of Scripture

Pak

2022

Int J Systematic Theology

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This article provides a study of John Calvin's treatment of the Old Testament prophets' language, images and metaphors to illuminate the distinctly visual character of his theology. It explores Calvin's theology of Scripture as shaped by the visual theology rooted in his exegesis of the Old Testament prophetic books. The author argues that the Old Testament prophets serve as supreme models for imitation of how to make God's Word come alive through visual images and powerful metaphors. Furthermore, the article draws connections between Calvin's engagement with the prophets' language of 'painting', 'mirror', 'vivid representation' and 'visible symbol' and his descriptions of biblical theophanies and the power of sacraments. Bringing these elements side by side, a vivid portrait emerges of Calvin's conception of Scripture as a visual sign. The author argues that this visual sign-character of Scripture undergirds a deeper commitment of Calvin's -a conviction of Scripture's sacramental character and functions. Consequently, the article argues that the visual features of Calvin's theology -where visual aspects unite his theologies of Scripture and the sacraments -set forth Scripture itself as a sacrament and call students of Calvin to take more seriously the visual and material commitments of his theology.

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“… 45. Calvin, 1563, 408; Calvin, 1574, 412. Adonner is a complex term, and appears to have a genealogy resonant with addiction .…”

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Scholarly Addiction:Doctor Faustusand the Drama of Devotion

Lemon

2016

Renaiss. Q.

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WhenThe English Faust Bookdescribes Faustus as addicted to study and Marlowe’sDoctor Faustusdepicts necromantic books as “ravishing,” these texts draw on classical and Renaissance notions of laudable addiction. Following its Latin origin in contract law,addictionappears in sixteenth-century writings as service, dedication, and devotion. Tracing invocations of addiction from Cicero to Perkins, this essay explores the influence of Calvin and Calvinist-minded Cambridge divines throughDoctor Faustus’spreoccupation with the challenge of addicted commitment. If Calvinists praise committed devotion, Marlowe challenges such views by staging the terror as well as the wonder of addictive release.

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The Sermons of M. John Calvin upon the Fifth Book of Moses called Deuteronomy

Cited by 12 publications

References 0 publications

Structure Activity Relationships for Reversible O₂ Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Structure Activity Relationships for Reversible O₂ Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Calvin's Visual Exegesis of Old Testament Prophecy: Figural Reading and the Sacramental Character of Scripture

Scholarly Addiction:Doctor Faustusand the Drama of Devotion

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The Sermons of M. John Calvin upon the Fifth Book of Moses called Deuteronomy

Cited by 12 publications

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Structure Activity Relationships for Reversible O2 Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Structure Activity Relationships for Reversible O2 Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Calvin's Visual Exegesis of Old Testament Prophecy: Figural Reading and the Sacramental Character of Scripture

Scholarly Addiction:Doctor Faustusand the Drama of Devotion

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Product

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Structure Activity Relationships for Reversible O₂ Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)

Structure Activity Relationships for Reversible O₂ Chemisorption by the Solid Phases of Co(salen) and Co(3F-salen)