We evaluate Polyakov loops and string tension in two-dimensional QED with both massless and massive N -flavor fermions at zero and finite temperature. External charges, or external electric fields, induce phases in fermion masses and shift the value of the vacuum angle parameter θ, which in turn alters the chiral condensate. In particular, in the presence of two sources of opposite charges, q and −q, the shift in θ is 2π(q/e) independent of N . The string tension has a cusp singularity at θ = ±π for N ≥ 2 and is proportional to m 2N/(N +1) at T = 0.Two-dimensional QED, the Schwinger model, with massive N -flavor fermions resembles fourdimensional QCD in various aspects, including confinement, chiral condensates, and θ vacua [1]- [11]. Much progress has been made recently in evaluating chiral condensates and string tension in the massive theory [12]-[16]. In this paper we shall show that the three phenomena, confinement, chiral condensates, and θ vacua, are intimately related to each other. In particular, the string tension in the confining potential is determined by the θ dependence of chiral condensates ψ − ψ .The behavior of the model is distinctively different, depending on whether N = 1 (one-flavor) or N ≥ 2 (multi-flavor), and on whether fermions are massless or massive. The massless (m = 0) theory is exactly solvable. ψ − ψ θ = 0 for N = 1, but ψ − ψ θ = 0 for N ≥ 2. [17,18] In either cases the string tension between two external sources of opposite charge vanishes [4,8,12]. In the massive (m = 0) theory ψ − ψ θ is proportional to m (N −1)/(N +1) cos 2N/(N +1) (θ/N ) at , 13]. For N ≥ 2 the dependence on m is non-analytic. It also has a cusp singularity at θ = ±π. A perturbation theory in fermion masses is not valid at low temperature.