The role of structural defects of cao-catalysts in the oxidative methane coupling

The catalytic oxidative coupling of methane (OCM) to C2 hydrocarbons with oxygen (O2‐OCM) has garnered renewed worldwide interest in the past decade due to the emergence of enormous new shale gas resources. However, the C2 selectivity of typical OCM processes is significantly challenged by overoxidation to COx products. Other gaseous reagents such as N2O, CO2, and S2 have been investigated to a far lesser extent as alternative, milder oxidants to replace O2. Although several authoritative review articles have summarized OCM research progress in depth, recent oxidative coupling developments using alternative oxidants (X‐OCM) have not been overviewed in detail. In this perspective, we review and analyze OCM research results reporting the implementation of N2O, CO2, S2, and other non‐O2 oxidants, highlighting the unique chemistries of these systems and their advantages/challenges compared to O2‐OCM. Current outlook and potential areas for future study are also discussed.

show abstract

Alternative Oxidants for the Catalytic Oxidative Coupling of Methane

Arinaga

Ziegelski

Marks

2021

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Alternative Oxidants for the Catalytic Oxidative Coupling of Methane

2021

View full text Add to dashboard Cite

show abstract

The influence of the reaction medium of oxidative methane coupling on the nature of bulk defects of the Li/CaO system

et al. 1992

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

The role of structural defects of cao-catalysts in the oxidative methane coupling

Cited by 4 publications

References 5 publications

Alternative Oxidants for the Catalytic Oxidative Coupling of Methane

Alternative Oxidants for the Catalytic Oxidative Coupling of Methane

Alternative Oxidants for the Catalytic Oxidative Coupling of Methane

The influence of the reaction medium of oxidative methane coupling on the nature of bulk defects of the Li/CaO system

Contact Info

Product

Resources

About