Abstract:BACKGROUND
Microbial leaching is an emerging ore extraction technology, especially for low‐grade ores. In sulfide and oxide ore bioleaching systems, Acidithiobacillus ferrooxidans is becoming a widely applied microorganism for mineral processing. Many studies are currently focusing on the vital role of A. ferrooxidans in facilitating the efficiencies of sulfur and iron species transformation for sulfide ore bioleaching. Existing research usually investigates the composite action of A. ferrooxidans and Fe(III) … Show more
“…Thus, the effective management of pulp density is a critical aspect of maximizing the process efficiency. Additionally, in the study "The Role of Acidithiobacillus ferrooxidans in the Oxidation of Fe(II) Pyrite in Bioleaching Processes" by [27] Kang, Jin-xing et al, it was found that Acidithiobacillus ferrooxidans significantly accelerate the oxidation of Fe(II) in pyrite, thereby enhancing the efficiency of the biological leaching of this sulfide ore.…”
This study presents findings regarding the kinetics of ferrous iron oxidation in solution mediated by Acidithiobacillus ferrooxidans bacteria within a continuous-flow bioreactor employing diverse types of immobilizers. The objective is to augment the rate of ferrous iron oxidation in solutions utilizing an immobilizer for Acidithiobacillus ferrooxidans strains. Immobilization represents a promising avenue for enhancing the efficiency of Fe2⁺ oxidation via acidophilic ferrooxidizing bacteria, leading to a several-fold increase in oxidation rate. A comparative analysis was conducted to evaluate the efficacy of different types of immobilizer in facilitating iron oxidation within a continuous-flow bioreactor, including the application of wood chips coated with Fe(OH)3. The results indicate that wood chips coated with iron hydroxide serve as effective type of immobilizer, facilitating the robust attachment of Acidithiobacillus ferrooxidans via electrostatic interactions between negatively charged bacteria and positively charged surfaces. Experimental investigations were conducted using novel immobilization matrices in pilot-scale tests simulating the underground borehole leaching (UBL) of uranium. The bioactivation of leaching solutions enhances the efficiency and environmental compatibility of UBL compared to conventional chemical oxidation methods. The relationships between redox potential and ferric iron content in bioactivated solutions during the UBL of uranium were delineated. The significance of this study lies in its elucidating the pivotal role of Fe2⁺ oxidation in uranium extraction processes, particularly in the context of UBL. By employing bioactivation mediated by Acidithiobacillus ferrooxidans, the study demonstrates not only enhanced uranium extraction efficiency, but also markedly improved environmental sustainability compared to traditional chemical oxidation methods. The findings reveal crucial correlations between redox potential and ferric iron concentration in bioactivated solutions.
“…Thus, the effective management of pulp density is a critical aspect of maximizing the process efficiency. Additionally, in the study "The Role of Acidithiobacillus ferrooxidans in the Oxidation of Fe(II) Pyrite in Bioleaching Processes" by [27] Kang, Jin-xing et al, it was found that Acidithiobacillus ferrooxidans significantly accelerate the oxidation of Fe(II) in pyrite, thereby enhancing the efficiency of the biological leaching of this sulfide ore.…”
This study presents findings regarding the kinetics of ferrous iron oxidation in solution mediated by Acidithiobacillus ferrooxidans bacteria within a continuous-flow bioreactor employing diverse types of immobilizers. The objective is to augment the rate of ferrous iron oxidation in solutions utilizing an immobilizer for Acidithiobacillus ferrooxidans strains. Immobilization represents a promising avenue for enhancing the efficiency of Fe2⁺ oxidation via acidophilic ferrooxidizing bacteria, leading to a several-fold increase in oxidation rate. A comparative analysis was conducted to evaluate the efficacy of different types of immobilizer in facilitating iron oxidation within a continuous-flow bioreactor, including the application of wood chips coated with Fe(OH)3. The results indicate that wood chips coated with iron hydroxide serve as effective type of immobilizer, facilitating the robust attachment of Acidithiobacillus ferrooxidans via electrostatic interactions between negatively charged bacteria and positively charged surfaces. Experimental investigations were conducted using novel immobilization matrices in pilot-scale tests simulating the underground borehole leaching (UBL) of uranium. The bioactivation of leaching solutions enhances the efficiency and environmental compatibility of UBL compared to conventional chemical oxidation methods. The relationships between redox potential and ferric iron content in bioactivated solutions during the UBL of uranium were delineated. The significance of this study lies in its elucidating the pivotal role of Fe2⁺ oxidation in uranium extraction processes, particularly in the context of UBL. By employing bioactivation mediated by Acidithiobacillus ferrooxidans, the study demonstrates not only enhanced uranium extraction efficiency, but also markedly improved environmental sustainability compared to traditional chemical oxidation methods. The findings reveal crucial correlations between redox potential and ferric iron concentration in bioactivated solutions.
“…Nevertheless, to the best of our knowledge, the potential application of microorganisms for RFB enhancement is barely to be investigated; only a few studies existed up to now. 23 , 24 The bacteria involved in ferrous oxidation/reduction processes are widely distributed in various natural and artificial ecosystems, which cause various environmental problems such as acid mine wastewater emission 25 , 26 and iron structure corrosion. 27 , 28 Certain iron reduction bacteria such as Geobacter have been widely employed in the remediation of soil and groundwater.…”
“…In addition, bioleaching provides more surface area and roughness which in turn contributes toward electrochemical characteristics. 21,22 Acidithiobacillus ferrooxidans is a wellknown bacterium for the oxidation of ferrous ions. However, adding other metallic atoms (Cu, Co, Mn, Mo, etc.)…”
Section: Introductionmentioning
confidence: 99%
“…Among these methods, controlled removal of iron can be achieved only through bacterial treatment, which is otherwise known as bioleaching, an ecofriendly method commonly used for mobilizing metals from waste, metal extraction, etc. In addition, bioleaching provides more surface area and roughness which in turn contributes toward electrochemical characteristics. , Acidithiobacillus ferrooxidans is a well-known bacterium for the oxidation of ferrous ions. However, adding other metallic atoms (Cu, Co, Mn, Mo, etc.)…”
In the quest for sustainable hydrogen production via water electrolysis, the development of high-performance, noble-metal-free catalytic systems is highly desired. Herein, we proposed an innovative strategy for the development of an electrocatalyst by refining the surface characteristics of a NiFeP alloy through microbiological techniques and subsequent enrichment of active sites by tailoring 3D hierarchical flower-like structures with intact and interconnected two-dimensional (2D) Co 3 O 4 . The resultant 3D Co 3 O 4 @NiFeP-5/24h has a porous structure comprised of intercrossed nanoparticles covering the entirety of the catalytic surface. This design ensures comprehensive electrolyte ion penetration and facilitates the release of gas bubbles while reducing bubble adhesion rates. Remarkably, the Co 3 O 4 @NiFeP-5/24h electrode demonstrates superior hydrogen evolution (HER) performance in an alkaline medium, characterized by its high stability, low overpotential (106 mV at a current density of 10 mA cm −2 ), and reduced Tafel slope (98 mV dec −1 ). Besides, the minimized interfacial contact resistance among the phases of electrode and electrolyte emphasizes the high HER performance of the 3D Co 3 O 4 @NiFeP-5/24h electrode. The innovative design and fabrication strategy employed herein holds significant potential for advancing the field of water-splitting electrocatalysis, offering a promising path toward the rational design and development of noblemetal-free electrocatalysts.
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