The Pb-Zn deposit at Jebel Ghozlane, in the Nappe zone (northern Tunisia), is hosted by Triassic dolostones and Eocene limestones and is located along faults and a thrust-sheet boundary. The sulfide mineralization of the deposit consists mainly of galena and sphalerite and occurs as vein, stockwork, breccia, dissemination and replacement ores. Three hydrothermal stages are involved in the formation of the ores: stage I is dominated by celestite-barite, hydrothermal dolomite DII, colloform sphalerite, and galena I; stage II consist of galena II; and stage III contains calcite. Galena in the deposit yielded average Pb ratios of 18.705, 15.667 and 38.734, respectively, suggesting a single upper crustal source reservoir for metals. Trace element data indicate the presence of Zn-and As-free galena and As-rich galena (with 0.2-0.5% As). Sphalerite contains 0.4% As, 0.7-0.9% Cd and 0.1-1.5% Fe. Microthermometric analysis of fluid inclusions in celestite shows that the deposit formed from fluids composed of heterogeneous mixtures of saline (19.5 Ϯ 1 wt% NaCl eq.) aqueous solutions sourced from basinal brines, and gaseous CO 2 -rich phases bearing low amounts of CH 4 , N 2 and/or H 2 S, at temperatures of 172 Ϯ 5°C.Keywords: fluid inclusion, Jebel Ghozlane, lead isotope, mineralogy, Northern Tunisia.
IntroductionSeveral base-metal deposits, which are similar to Mississippi Valley-type (MVT) deposits, exist in the Nappe zone in Northern Tunisia (Mansouri, 1980;Rouvier et al., 1985;Slim-Shimi & Tlig, 1993;Decrée et al., 2008b;Abidi et al., 2010; Jemmali et al., 2011a, b) (Fig. 1). Those deposits comprise about 10% of the total F-Pb-Zn-Ba Tunisian reserves. Most of the base-metal deposits in the Nappe zone are located close to salt diapirs ( Fig. 1), and they are likely associated either with a Late Miocene orogeny (cf. Rouvier et al., 1985;Burollet, 1991;Jemmali et al., 2011b) or with Neogene volcanism (Rouvier et al., 1985;Slim-Shimi & Tlig, 1993;Decrée et al., 2008a, b; Jemmali et al., 2011a, b). Many basemetal deposits in the Nappe zone consist of stratabound and vein bodies that are characterized by open-space filling ores in karst structures within or at Nicolini, 1968;Rouvier, 1971;Mansouri, 1980;Rouvier et al., 1985;Slim-Shimi & Tlig, 1993). This and the likely association of the deposits with either the Late Miocene orogeny or the Neogene volcanism suggest that hydrothermal karstification, which has been reported at other MVT deposits elsewhere (e.g. Fowler, 1994;Bouch et al., 2006;Gutzmer, 2006), was an important mechanism, rather than replacement, for generating mainly pre-mineralization porosity in the Triassic dolostones (cf. Nicolini, 1968;Rouvier, 1971;Mansouri, 1980;Rouvier et al., 1985;Slim-Shimi & Tlig, 1993). There are two major groups of base-metal deposits in the Nappe zone (Rouvier et al., 1985): (i) As-Sb bearing Pb-Zn deposits hosted in the continental Neogene series or in the rocks contacting the Neogene series (e.g. Aïn Allega, Sidi Embarek, Jebel Hallouf-Sidi Bou Aouane, Bazina, Semene,...