The role of defects in the properties of functional coordination polymers

Castillo‐Blas, Celia; Montoro, Carmen; Platero‐Prats, Ana E.; Ares, Pablo; Amo‐Ochoa, Pilar; Conesa, Javier; Zamora, Félix

doi:10.1016/bs.adioch.2020.03.002

Cited by 14 publications

(6 citation statements)

References 112 publications

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“…On the presence of (missing-linker) defects in coordination polymers or metal−organic frameworks the reader is referred to. [48][49][50] Finally, the carboxylate groups of the BTC 3− linker were allowed to rotate with respect to the plane of the aromatic ring. The background was modeled through a Chebyshev-type polynomial function.…”

Section: Synthesis Of Eu(btc)−1: [Eu(btc)(h 2 O)mentioning

confidence: 99%

Highly Sensitive, Multiparametric Thermal History Phosphor Based on An Eu(BTC) Architecture

Szymczak,

Mauri,

Galli

et al. 2024

Adv Funct Materials

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The capacity to discern the highest temperature that an object is subjected to is a crucial diagnostic tool. Consequently, the pursuit of materials that enable the luminescence‐based investigation of the thermal history of an object with high sensitivity is of great importance from the functional applications standpoint. This study aims to present a multiparametric thermal history phosphor based on the luminescent coordination polymer [Eu(BTC)(H2O)6] [Eu(BTC)‐1, where H3BTC = 1,3,5‐benzenetricarboxylic acid]. The progressive dehydration that Eu(BTC)‐1 undergoes as a function of temperature increase in the 343–425 K range results in significant alterations in both the shape of the Eu3+ ions emission spectrum and the depopulation kinetics of their 5D0 level. Based on this occurrence, a thermal history phosphor with an unprecedentedly high relative sensitivity of 11.3% K−1 in ratiometric mode, and 1.8% K−1 in lifetime‐based mode, is developed. The outcomes of this research are expected to stimulate a wide interest in the exploitation of (porous) coordination polymer‐type materials for the development of thermal history phosphors.

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Section: Synthesis Of Eu(btc)−1: [Eu(btc)(h 2 O)mentioning

confidence: 99%

Highly Sensitive, Multiparametric Thermal History Phosphor Based on An Eu(BTC) Architecture

Szymczak,

Mauri,

Galli

et al. 2024

Adv Funct Materials

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“…For some recent reviews illustrating their diversity, see ref. [67][68][69][70][71], where more comprehensive listing of background material is given. For oligo-zwitterion ligands, at least three points of interest related to their use in the synthesis of coordination polymers and frameworks arise:…”

Section: Oligo-zwitterions and The Formation Of Coordination Polymers...mentioning

confidence: 99%

Oligozwitterions in coordination polymers and frameworks – a structural view

Baklouti

Harrowfield

2023

Dalton Trans.

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“…Nanotubes, nanofibers, nanowires, nanorods and nanofilaments are grouped under this category. These are amorphous or crystalline (mono or poly) materials [16,17]. 1D carbon induces high percolation and reduces the electron transportation distance for enhancing the electrical conductivity [11].…”

Section: Multidimensional Nanostructured Carbonmentioning

confidence: 99%

Nanocarbon in Sodium‐ion Batteries – A Review. Part 2: One, Two, and Three‐dimensional Nanocarbons

2023

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Nanocarbons play a significant role in the development of alternative, clean and sustainable energy technologies. The utility of low‐dimensional nanostructured carbons (one‐, two‐ and three‐dimensional) in the new generation of batteries have shown great potential due to their physicochemical and electrochemical properties as well as high safety. The electrodes made from nanostructured carbon materials with different dimensions, size and structures offer enhanced ionic transport and electronic conductivity as compared to conventional batteries. They also enable the occupation of all intercalation sites available in the particle which leads to high specific capacities, fast ion diffusion, superior rate capability and long‐term cyclability. The carbonaceous nanosized active materials are important to enhance the electrical conductivity of the electrode materials and buffer the structural change and strain during sodium insertion and extraction. Application potentialities of different low‐dimensional nanostructured carbons in sodium‐ion batteries (SIBs) are discussed in this part II. It also deals with the modifications made on the carbonaceous material by doping with heteroatoms, expressing diversified morphologies with porous materials or compositing with organic or inorganic species.

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The role of defects in the properties of functional coordination polymers

Cited by 14 publications

References 112 publications

Highly Sensitive, Multiparametric Thermal History Phosphor Based on An Eu(BTC) Architecture

Highly Sensitive, Multiparametric Thermal History Phosphor Based on An Eu(BTC) Architecture

Oligozwitterions in coordination polymers and frameworks – a structural view

Nanocarbon in Sodium‐ion Batteries – A Review. Part 2: One, Two, and Three‐dimensional Nanocarbons

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