“…Therefore, the deep colour system of direct dyes usually results in a large amount of dye molecules in the dye wastewater. On the other hand, because the direct dyes have large molecules, their adsorption onto biomass may be not optimal [53].…”
Section: Study Of Adsorption Of Direct Red 75 (Dr75)mentioning
“…Therefore, the deep colour system of direct dyes usually results in a large amount of dye molecules in the dye wastewater. On the other hand, because the direct dyes have large molecules, their adsorption onto biomass may be not optimal [53].…”
Section: Study Of Adsorption Of Direct Red 75 (Dr75)mentioning
“…Various ion-exchange resins derived from sugar cane bagasse, waste paper, polyamide wastes, chitin, etc., were applied as adsorbents for removal of colour and other organics. [20][21][22][23][24] Colour-removal efficiency with these ion-exchange resins was comparable with that achieved using activated carbon.…”
“…Modification reactions, including cross‐linking and/or functionalization, have been tried to enhance the adsorbent stability and/or adsorption capacity. As a matter of fact, many chemical modification methods have been developed to improve adsorption abilities . In recent years, the utilization of carbon‐based materials, such as graphene and multiwalled carbon nanotubes as adsorbent in SPE procedure, are good choice to obtain good recovery and high enrichment factor (EF).…”
A green biocomposite of sunflower stalks and graphitic carbon nitride nanosheets has been applied as a solid-phase extraction adsorbent for sample preparation of five polycyclic aromatic hydrocarbons in different solutions using high-performance liquid chromatography with ultraviolet detection. Before the modification, sunflower stalks exhibited relatively low adsorption to the polycyclic aromatic hydrocarbons extraction. The modified sunflower stalks showed increased adsorption to the analytes extraction due to the increase in surface and existence of a π-π interaction between the analytes and graphitic carbon nitride nanosheets on the surface. Under the optimal conditions, the limits of detection and quantification for five polycyclic aromatic hydrocarbons compounds could reach 0.4-32 and 1.2-95 ng/L, respectively. The method accuracy was evaluated using recovery measurements in spiked real samples and good recoveries from 71 to 115% with relative standard deviations of <10% have been achieved. The developed method was successfully applied for polycyclic aromatic hydrocarbons determination in various samples-well water, tap water, soil, vegetable, and barbequed meat (kebab)-with analytes contents ranging from 0.065 to 13.3 μg/L. The prepared green composite as a new sorbent has some advantages including ease of preparation, low cost, and good reusability.
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