The Reduction of Metallabenzenes: Different Scenarios Highly Dependent on the Central Group 14 Elements, Si vs. Ge
Shingo Tsuji,
Norihiro Tokitoh,
Hiroko Yamada
et al.
Abstract:In order to synthesize a silabenzenyl anion, in which the anionic carbon atom of a phenyl anion was replaced with a silicon atom, the reductive dearylation reaction of 1‐Tbt‐2‐tert‐butyl‐silabenzene (Tbt=2,4,6‐tris[bis(trimethylsilyl)methyl]phenyl) with KC8 was attempted. Unexpectedly, this reaction resulted in the formation of a dianion species without the elimination of the Tbt group. This is totally different from the reactions of Tbt‐substituted germa‐ or stannabenzene with KC8, which resulted in the forma… Show more
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