The redox potential of Pu containing acidic solutions and the fate of "Pu(IV)-colloids": Direct measurement versus optical absorption spectroscopy

Icker, M.; Walther, Clemens; Neck, V.; Geckeis, H.

doi:10.1088/1757-899x/9/1/012060

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2022

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“…These colloids and polymers also take part in the Pu(IV) to Pu(V) oxidation with its following disproportionation. 23,30 These small Pu polymers detected by ESI-TOF might be also responsible for the equilibration between the Pu(III)/Pu(IV) and Pu(V)/Pu(VI) plutonyl species. 23 However, to determine exactly if other oxidation states of Pu are present, one needs to use a direct method of probing Pu electronic 5f states at real state conditions.…”

Section: Introductionmentioning

confidence: 99%

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To form or not to form: PuO₂ nanoparticles at acidic pH

Gerber

Romanchuk

Weiß

et al. 2022

Environ. Sci.: Nano

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Section: Introductionmentioning

confidence: 99%

“…These colloids and polymers also take part in the Pu( iv ) to Pu( v ) oxidation with its following disproportionation. 23,30 These small Pu polymers detected by ESI-TOF might be also responsible for the equilibration between the Pu( iii ) / Pu( iv ) and Pu( v ) / Pu( vi ) plutonyl species. 23…”

Section: Introductionmentioning

confidence: 99%