In recent years, chaotic systems have begun to take a substantial place in literature due to increasing importance of secure communication. Chaotic synchronization which has emerged as a necessity for secure communication can now be performed with many different methods. This study purposes the Master-Slave synchronization via active controller and real time simulation of five different chaotic systems such as Lorenz, Sprott, Rucklidge, Moore-Spiegel, Rössler. Master slave synchronization was performed because of synchronization realized between the same type of chaotic systems with different initial parameters and also because of the systems were expected to behave similarly as a result of synchronization. Active control method was used to amplify the difference signal between master and slave systems which have different initial parameters and to return back synchronization information to the slave system. The real time simulation and synchronization of the master and slave systems performed successfully in LabVIEW environment. Furthermore, for the real time implementation, analogue outputs of NI-DAQ card used and real time results also were observed on an oscilloscope and secure communication application using sinusoidal signal and an image encryption application achieved successfully.