Abstract:. Can. J. Chem. 54, 2557Chem. 54, (1976. Several acylate salts and noncyclic carbene complexes of manganese and rhenium, containing organogermanium ligands, have been prepared via the reactions of the cyclic germoxycarbene complexes of empirical formula Ph2GeM(C0)4COMe (M = Mn, Re) with the nucleophiles methyllithium or methoxide ion. In each case the observed product could be rationalized in terms of nucleophilic attack at germanium. Treatment of Ph2GeRe(C0)4COMe with methyllithium, followed by ethylation w… Show more
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