The Reaction of Water Vapor and Carbon Vapor Produced by Laser Irradiation

Kim, Pil Hyon; Taki, Ko; Namba, Susumu

doi:10.1246/bcsj.48.2953

Search citation statements

Order By: Relevance

Paper Sections

Select...

Introduction1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1985

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

(1 citation statement)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…C0 2 and CH 4 are formed in trace amounts only [9]. SHEVLIN, et al [10] reported an experimental and theoretical investigation of atomic carbon generated by thermolysis of 5-diazotetrazole in the presence of water vapour.…”

Section: Introductionmentioning

confidence: 99%

Reaction of Recoiling Carbon Atoms with Water Vapour

1985

View full text Add to dashboard Cite

Hot atom chemistry ¡Recoil carbon/Carbon-11 ("C)/ Atomic carbon • water vapour system /FormaldehydeSummary The chemical reactions of recoil "C with H 2 0 vapour (28 mbar) were studied at ambient temperature in the pure system and after addition of 1 bar neon moderator. Atomic carbon was generated in situ via the 1 Όίρ,αρη) 11 C-reaction and via recoil-implantation from a thin BN-layer after the 14 N (ρ, a)" C process. The chemical consequences were followed over a radiation dose range from 5 · 10" 2 to 34 eV per target molecule. Typical products were "CO, "CH 4 and "C0 2 . The yield of "CO was found to be 98 % at the lowest dose. With increasing dose, the yield of 11 CO decreased, giving rise to the secondary radiolytic products 11 CO 2 and 1 'CH,,. It is assumed that a primarily formed carbonwater complex decomposes into 11 CO and Η,. Formaldehyde was not formed.

show abstract

Section: Introductionmentioning

confidence: 99%