The reaction of trichloroiodomethane with some organometallic compounds of group VB elements

Pullman, Bernard; West, BO

doi:10.1016/0022-1902(61)80115-2

Cited by 8 publications

(3 citation statements)

References 20 publications

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“…Isomeric transition induced yields of 130 I in CC1 4 were determined to be the same ( . It was, therefore, interesting that 130 I m (IT) 130 I and 129 I (η, γ) 130 I induced organic retentions would be low (less than 5%) at all mole fractions halogen studied, especially since the most probable product, CC1 3 I is a stable compound [13]. In 131 I 2 -CC1 4 radiation damage studies, we obtained yields of iodine in organic combinations as high as 13 percent at 3.0 χ IO -4 m. f. I 2 for 30 min irradiation.…”

Section: Resultsmentioning

confidence: 98%

Substituent Effects in Iodine-130 Reactions Activated by (n,y) and (IT) with Various Polyhalomethanes

Parks

Rack

1968

Radiochimica Acta

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Section: Resultsmentioning

confidence: 98%

Substituent Effects in Iodine-130 Reactions Activated by (n,y) and (IT) with Various Polyhalomethanes

Parks

Rack

1968

Radiochimica Acta

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“…Triazine 6 was shown to be thermally stable at 45°in the dark. Irradiation of tetramethyltetrazene (8) in carbon tetrachloride again gave chloroform as the only solvent-soluble photoproduct and a precipitate of amine hydrochloride. Reaction, however, was inefficient.…”

Section: Resultsmentioning

confidence: 99%

Photochemical reaction of dimethylamine in polychloromethanes. Photochemical synthesis of bis(dimethylamino)methane

Hancock¹,

Dickinson²

1974

J. Org. Chem.

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Irradiation of ca. 1.0 M solutions of dimethylamine in carbon tetrachloride at 300 nm and 35°g ave IV.lV.A'.lV'-tetramethylmethanediamine (22 mol %), dimethylamine hydrochloride (32 mol %), and chloroform (25 mol %), plus lesser amounts of methylamine. Quantum yields at zero conversion were 4.7 mol einstein-1 for disappearance of dimethylamine, and 1.2, 1.1, and 1.2 for appearance of diamine, amine hydrochloride, and chloroform, respectively. Similar reactions of dimethylamine were observed in chloroform and , , -trichlorotoluene, but with longer irradiation times. Diamine formed in irradiations of dimethylamine in deuteriochloroform showed no deuterium incorporation. A mechanism involving photodissociation of an amine-halocarbon charge-transfer complex, followed by disproportionation and/or combinations of dimethylamine' radicals, and, finally, by aminal disproportionation is supported by control experiments, quantum yields, and the protochemistry of potential and actual intermediates. The 4:1 reaction stoichiometry of dimethylamine to diamine corresponds to ca. 88% of theoretical yield for production of diamine.

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“…this structure.2 However, conductometric measurements indicate the existence of ionic species in polar solvents, and the following ionic structures have been proposed: R3Y+Xand R8Y+X3-(Y = P, As, Sb, and Bi; X = Brandi). [3][4][5][6][7][8] The donor properties of the alkyl or aryl derivatives…”

Section: Introductionmentioning

confidence: 99%

Assignment of MC Stretching and MCN Bending Frequencies in Metal Cyanide Complexes

Jones¹

1965

Inorg. Chem.

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The reaction of trichloroiodomethane with some organometallic compounds of group VB elements

Cited by 8 publications

References 20 publications

Substituent Effects in Iodine-130 Reactions Activated by (n,y) and (IT) with Various Polyhalomethanes

Substituent Effects in Iodine-130 Reactions Activated by (n,y) and (IT) with Various Polyhalomethanes

Photochemical reaction of dimethylamine in polychloromethanes. Photochemical synthesis of bis(dimethylamino)methane

Assignment of MC Stretching and MCN Bending Frequencies in Metal Cyanide Complexes

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