The reaction of Ru3(CO)12 with 1,4-dichloro-but-2-yne in basic methanolic solution. Synthesis and crystal structure of (μ-H)2Ru3(CO)9{μ3-η2-[H2CC(H)CCC(O)OCH3]}

Gervasio, Giuliana; Marabello, Domenica; Sappa, Enrico; Secco, Andrea

doi:10.1016/j.jorganchem.2004.12.033

Cited by 14 publications

References 32 publications

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The Thermolysis of Ru₃(CO)₁₂ with Carboxylic Acids Revisited: Stepwise Assembly of Ru₂ to Ru₆ Cluster Frameworks

et al. 2016

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Thermolysis of Ru 3 (CO) 12 with carboxylic acids directly accessed a large variety of low valence ruthenium carbonyl complexs. Under the conditions of the reaction firstly reported by J. Lewis, 3 equivalents of acids were employed to assembly sawhorsetype dirutheniumtetra carbonyl complex. Six Ru 3 -Ru 6 ruthenium clusters were unexpectedly isolated in the reaction of Ru 3 (CO) 12 with 1 equivalent of carboxylic acids under thermal condition. The reaction of Ru 3 (CO) 12 with ten kind of carboxylic acids were systematically investigated. The reactions of Ru 3 (CO) 12 with non-coordinative carboxylic acids afforded b-H 2 Ru 4 (CO) 13 (2), Ru 6 (m 6 -C)(m-CO)(CO) 16 (3) and then to Ru 6 (m 6 -C)(m-CO)(CO) 13 (h 6 -C 6 H 5 CH 3 ) (4), respectively. The further experiments indicated that the formation of 3 was attributed to the assembly of tetraruthenium carbonyl dihydrid 2 with polymeric sawhorse diruthenium intermediate [Ru 2 (CO) 4 (OOR) 2 ] n (R = alkyl, aryl). The thermolysis of phenylpropiolic acid with Ru 3 (CO) 12 unveiled an alternative pathway to access Ru 6 skeleton. The triruthenium cluster [(m-H)Ru 3 (CO) 9 (m 3 -h 2 -(?)-C CC 6 H 5 )] (5) and butterfly tetraruthenium compound Ru 4 (CO) 12 (HC CC 6 H 5 ) (6) were identified as the key intermediates in the construction of compound 3.[a] J.

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The Thermolysis of Ru₃(CO)₁₂ with Carboxylic Acids Revisited: Stepwise Assembly of Ru₂ to Ru₆ Cluster Frameworks

et al. 2016

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Reactions of Ru3(CO)12 with Ene-yne and Alkoxy-silyl Functionalized Compounds. The Crystal Structure of (μ-H)Ru3(CO)9[μ3-η2-HC=N(CH2)3Si(OEt)3]

et al. 2006

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The Reactions of Two New Alkoxy-silyl Functionalized Alkynes with M3(CO)12 {M = Fe, Ru} and Co2(CO)8. Spectroscopic Identification of the Products

2007

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The reaction of Ru3(CO)12 with 1,4-dichloro-but-2-yne in basic methanolic solution. Synthesis and crystal structure of (μ-H)2Ru3(CO)9{μ3-η2-[H2CC(H)CCC(O)OCH3]}

Cited by 14 publications

References 32 publications

The Thermolysis of Ru₃(CO)₁₂ with Carboxylic Acids Revisited: Stepwise Assembly of Ru₂ to Ru₆ Cluster Frameworks

The Thermolysis of Ru₃(CO)₁₂ with Carboxylic Acids Revisited: Stepwise Assembly of Ru₂ to Ru₆ Cluster Frameworks

Reactions of Ru3(CO)12 with Ene-yne and Alkoxy-silyl Functionalized Compounds. The Crystal Structure of (μ-H)Ru3(CO)9[μ3-η2-HC=N(CH2)3Si(OEt)3]

The Reactions of Two New Alkoxy-silyl Functionalized Alkynes with M3(CO)12 {M = Fe, Ru} and Co2(CO)8. Spectroscopic Identification of the Products

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The reaction of Ru3(CO)12 with 1,4-dichloro-but-2-yne in basic methanolic solution. Synthesis and crystal structure of (μ-H)2Ru3(CO)9{μ3-η2-[H2CC(H)CCC(O)OCH3]}

Cited by 14 publications

References 32 publications

The Thermolysis of Ru3(CO)12 with Carboxylic Acids Revisited: Stepwise Assembly of Ru2 to Ru6 Cluster Frameworks

The Thermolysis of Ru3(CO)12 with Carboxylic Acids Revisited: Stepwise Assembly of Ru2 to Ru6 Cluster Frameworks

Reactions of Ru3(CO)12 with Ene-yne and Alkoxy-silyl Functionalized Compounds. The Crystal Structure of (μ-H)Ru3(CO)9[μ3-η2-HC=N(CH2)3Si(OEt)3]

The Reactions of Two New Alkoxy-silyl Functionalized Alkynes with M3(CO)12 {M = Fe, Ru} and Co2(CO)8. Spectroscopic Identification of the Products

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The Thermolysis of Ru₃(CO)₁₂ with Carboxylic Acids Revisited: Stepwise Assembly of Ru₂ to Ru₆ Cluster Frameworks

The Thermolysis of Ru₃(CO)₁₂ with Carboxylic Acids Revisited: Stepwise Assembly of Ru₂ to Ru₆ Cluster Frameworks