The reaction of cyclopentadienylidine, fluorenylidene and tetrachlorocyclopentadienylidene with alcohols. A laser flash photolysis study

Olson, David R.; Platz, Matthew S.

doi:10.1002/(sici)1099-1395(199611)9:11<759::aid-poc834>3.0.co;2-o

J. Phys. Org. Chem.

1996

DOI: 10.1002/(sici)1099-1395(199611)9:11<759::aid-poc834>3.0.co;2-o

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The reaction of cyclopentadienylidine, fluorenylidene and tetrachlorocyclopentadienylidene with alcohols. A laser flash photolysis study

David R. Olson

¹

,

Matthew S. Platz

²

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Cited by 17 publications

(2 citation statements)

References 27 publications

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“…The triplet state of FY (T-FY) is 2–3 kcal/mol more stable than its lowest singlet state (S-FY) . T-FY could be isolated in cryogenic matrices and characterized by EPR, IR, and UV–vis spectroscopy. − In solution, FY was characterized by time-resolved spectroscopy as a transient species with nanosecond lifetimes. − Here, we describe the STM characterization of FY stabilized on a Ag(111) surface.…”

Section: Introductionmentioning

confidence: 99%

Controlling Reactivity—Real-Space Imaging of a Surface Metal Carbene

Mieres‐Pérez

¹

,

Lucht

²

,

Trosien

³

et al. 2021

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Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

“…The triplet state of FY (T-FY) is 2–3 kcal/mol more stable than its lowest singlet state (S-FY) . T-FY could be isolated in cryogenic matrices and characterized by EPR, IR, and UV–vis spectroscopy. − In solution, FY was characterized by time-resolved spectroscopy as a transient species with nanosecond lifetimes. − Here, we describe the STM characterization of FY stabilized on a Ag(111) surface.…”

Section: Introductionmentioning

confidence: 99%

Controlling Reactivity—Real-Space Imaging of a Surface Metal Carbene

Mieres‐Pérez

¹

,

Lucht

²

,

Trosien

³

et al. 2021

Get access via publisher Add to collection Cite

Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

“…Carbenes 5 and 6 had been previously isolated and spectroscopically characterized in inert gas matrices. − Several bimolecular reactions of these carbenes were studied under the conditions of matrix isolation − or by laser flash photolysis …”

Section: Introductionmentioning

confidence: 99%

Reactions of Cyclopentadienylidenes with CF₃I: Electron Bond Donation versus Halogen Bond Donation of the Iodine Atom

Henkel

¹

,

Trosien

²

,

Mieres‐Pérez

³

et al. 2018

Get access via publisher Add to collection Cite

Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

Carbene protonation

Kirmse¹

2001

Advances in Carbene Chemistry

Get access via publisher Add to collection Cite

Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.

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