The reaction of benzothiazole sulfenamide with (TMS)3SiH: An example of degenerate-branched chain process

Varlamov, V. T.; Ferreri, Carla; Chatgilialoglu, Chryssostomos

doi:10.1016/j.jorganchem.2005.01.031

Cited by 7 publications

(3 citation statements)

References 22 publications

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“…The rate constant of dialkylaminyl radicals is similar to that of the analogous reaction of secondary alkyl radical (i.e., ∼ 3 × 10 5 M −1 s −1 at 76 °C). 19 The rate constants of tert-butoxyl and cumylperoxyl radicals are 1.1 × 10 8 M −1 s −1 at 24 °C and 66 M −1 s −1 at 73 °C, respectively. 20,21 Notably, molecular oxygen reacts spontaneously with (TMS) 3 SiH to give (TMS) 3 Si • and HOO • radicals (see section 4.4).…”

Section: Peculiarities Of (Tms) 3 Sihmentioning

confidence: 93%

Thirty Years of (TMS)₃SiH: A Milestone in Radical-Based Synthetic Chemistry

et al. 2018

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This review is an update on tris(trimethylsilyl)silane, TTMSS, in organic chemistry, focusing on the advancements of the past decade. The overview includes a wide range of chemical processes and synthetic strategies under different experimental conditions, including functional group insertion and transformations, as well as preparation of complex molecules, natural products, polymers, surfaces, and new materials. These results reveal how TTMSS has matured over the past 30 years, and they further establish its value as a free radical reagent with widespread academic and industrial applications.

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Section: Peculiarities Of (Tms) 3 Sihmentioning

confidence: 93%

Thirty Years of (TMS)₃SiH: A Milestone in Radical-Based Synthetic Chemistry

et al. 2018

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“…For related structures, see Bethge et al (2008); Siracusa et al (2008); Solar et al (2008); Varlamov et al (2005).…”

Section: Related Literaturementioning

confidence: 99%

“…Some related compounds involving the 2-mercaptobenzothiazole and its derivatives has reported previously (Varlamov et al, 2005;Solar et al, 2008;Siracusa et al 2008;Bethge et al, 2008). The crystal structure of the title compound consists of tris(2-hydroxyethyl)ammonium cations and benzothiazole-2-thiolate anions (Fig.…”

Section: S1 Commentmentioning

confidence: 99%