The Reaction Between Organomagnesium Halides and the Aryl Esters of Boric, Carbonic, Silicic and Phosphoric Acids

Organic Compounds Of Boron

“…CiHi-216 (3,19,38,80,116,130,154,155,157,177,180,186,191,197,198,199,200,210,236,240,241,244,251,263,265,311,328,335) o-CHaCaHa-168 (180,183,241,335) m-CHaCaHa-…”

Copper-Catalyzed Cyanation of Aryl- and Alkenylboronic Reagents with Cyanogen Iodide

“…Organoboronic acid derivatives are the most widely used class of building blocks for transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions . Conventional methods for the synthesis of organoboronic compounds typically start from the corresponding halide . However, in 2002, Ishiyama, Miyaura, and Hartwig developed an iridium-catalyzed C­(sp 2 )–H borylation reaction of arenes that enabled the halide-free synthesis of arylboronic compounds with completely different regioselectivity to that generated by using halide-based methods .…”

A study of the reaction of perfluoroalkyl Grignard reagents with phosphoryl chloride and phenylphosphonic dichloride

“…By comparison triarylphosphates react with alkyl and aryl Grignards in a similar manner to phosphoryl chloride. 32 Thiophosphoryl chloride reacts with aryl Grignards to form triarylphosphine oxides. 33 With low molecular weight primary alkyl Grignards, tetraalkylbiphosphine disulfides are generally formed instead.…”