The pulse radiolysis of 1-propanol at 147 to 300 K

Abstract

Using -20 ns electron pulses the spectra and kinetics of the electron and an absorption in the uv in I-propanol have been determined at temperatvres from 147 to 300 K. The uv absorptio~~ is attributed to the hydroxy propyl radical,CH3CH2CHOH; it is formed within -20 ns over this temperature range and disappears by second order kinetics. The results for the formation of the solvated electron are in agreement with those of Baxendale and Wardman. The temperature dependence of both the radical-radical reaction and the reaction of the solvated electron with N 2 0 is very nearly the same as that of TItl.

Photoreduction of IrCl62? complex in alcohol solutions and its reaction with hydroxyalkyl radicals

“…Thus, Gilles and Boyd [48] have established that the recombination of (CH 3 ) 2 иCOH radicals, arising upon pulse radiolysis of isopropanol within the temperature range of obey the dependence.…”