The pseudocapacitance and sensing materials constructed by Dawson/basket-like phosphomolybdate

He, Lu-Lu; Cui, Liping; Yu, Kai; Lv, Jinghua; Ma, Yajie; Tian, Ran; Zhou, Baibin

doi:10.1016/j.jssc.2022.123578

Cited by 3 publications

(1 citation statement)

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“…The data in Table S1 show that Dawson POMs are widely used in photocatalysis and sensing, and the highly negatively charged, oxygen-rich surface of Dawson-type POMs can enhance the charge separation and electron transmission efficiency [ 24 , 25 , 26 ], which is beneficial for improving the performance of supercapacitors and H 2 O 2 sensors. In recent years, our group has reported several cases of Dawson-type POM compounds with an excellent supercapacitors performance synthesized using the hydrothermal method [ 27 , 28 , 29 , 30 , 31 ]. However, its large solubility in electrolytes or water and low intrinsic conductivity hinder its practical application as a solid electrode material in supercapacitors and sensing.…”

Section: Introductionmentioning

confidence: 99%

Nanomaterial with Core–Shell Structure Composed of {P2W18O62} and Cobalt Homobenzotrizoate for Supercapacitors and H2O2-Sensing Applications

Zhang

Lin

et al. 2023

Nanomaterials

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Designing and preparing dual-functional Dawson-type polyoxometalate-based metal–organic framework (POMOF) energy storage materials is challenging. Here, the Dawson-type POMOF nanomaterial with the molecular formula CoK4[P2W18O62]@Co3(btc)2 (abbreviated as {P2W18}@Co-BTC, H3btc = 1,3,5-benzylcarboxylic acid) was prepared using a solid-phase grinding method. XRD, SEM, TEM et al. analyses prove that this nanomaterial has a core–shell structure of Co-BTC wrapping around the {P2W18}. In the three-electrode system, it was found that {P2W18}@Co-BTC has the best supercapacitance performance, with a specific capacitance of 490.7 F g−1 (1 A g−1) and good stability, compared to nanomaterials synthesized with different feedstock ratios and two precursors. In the symmetrical double-electrode system, both the power density (800.00 W kg−1) and the energy density (11.36 Wh kg−1) are greater. In addition, as the electrode material for the H2O2 sensor, {P2W18}@Co-BTC also exhibits a better H2O2-sensing performance, such as a wide linear range (1.9 μM–1.67 mM), low detection limit (0.633 μM), high selectivity, stability (92.4%) and high recovery for the detection of H2O2 in human serum samples. This study provides a new strategy for the development of Dawson-type POMOF nanomaterial compounds.

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