The Production of Sodium Hydride and Some of its Reactions

Hansley, V. L.; Carlislie, P.J.

doi:10.1021/cen-v023n015.p1332

Cited by 19 publications

(9 citation statements)

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“…distillate, which was identified as N-formylpiperidine by its complex with mercuric chloride. 7 The yield of constant-boiling distillate was 88 g. or 78%.…”

Section: Methodsmentioning

confidence: 99%

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine¹

Sternberg¹,

Wender²,

Friedel³

et al. 1953

J. Am. Chem. Soc.

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The polyiodide ions mentioned here have been encountered by previous investigators in both inorganic and organic solids. Thus, for example, compounds represented by the formulas 3• 20, Rbl3, KI7-H20 and KI9-3C6H6 have been isolated.JS In addition, organic compounds containing the triiodide, heptaiodide or enneaiodide ion have also been mentioned in the literature. As examples of these we have the compounds (CH3)4NI3,19 (C2H5)4PI3,20 (C2H6)R4NI719a and (CH3)4NI9.19•21

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“…distillate, which was identified as N-formylpiperidine by its complex with mercuric chloride. 7 The yield of constant-boiling distillate was 88 g. or 78%.…”

Section: Methodsmentioning

confidence: 99%

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine¹

Sternberg¹,

Wender²,

Friedel³

et al. 1953

J. Am. Chem. Soc.

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“…2,2-Diphenylpentene-4-ol-l.-The reduction was similar using 1.8 g. (0.05 mole) of lithium aluminum hydride and 5.0 g. (0.02 mole) of allyldiphenylacetic acid. 3 The residue from concentration of the ethereal extracts was crystallized from Skelly B. The product weighed 4.6 g. (95%) and…”

Section: Methodsmentioning

confidence: 99%

High Molecular Weight Alkyl Amine Nitrites and Hydrohalides¹

Petrillo¹

1951

J. Am. Chem. Soc.

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NOTES 2381We estimate the over-all uncertainty in our combustion value as less than 0.025%, corresponding to a limit of 370 cal. for the molal heat of combustion. In this connection it is interesting to note that the earlier values of Stohmann,6 Roth and and BriilP now appear surprisingly good, as these exceed our present result by only 0.06 0.05 and 0.03010, respectively. On the other hand, the value reported by Barker' in 1925 is 0.45% higher than our result.

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“…Substitution of Hydrogen by Carbon The acetoacetic ester condensation has been applied to fatty acid esters, leading to the formation of 2-acyl esters. Various basic condensing agents were employed, 2RCH2COOC2H5 -> RCH2COCHRCOOC2H8 including sodium alkoxides (94,182), Grignard reagents (mesitylmagnesium bromide) (504), diisopropylaminomagnesium bromide (178), and sodium hydride (124,218). Saponification of the keto ester is accom- panied by decarboxylation with formation of the symmetrical higher aliphatic ketone.…”

Section: Substitution Of Hydrogen By Nitrogenmentioning

confidence: 99%

Reactions of the Hydrocarbon Chain of Fatty Acids.

Harwood¹

1962

Chem. Rev.

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The Production of Sodium Hydride and Some of its Reactions

Cited by 19 publications

References 0 publications

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine¹

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine¹

High Molecular Weight Alkyl Amine Nitrites and Hydrohalides¹

Reactions of the Hydrocarbon Chain of Fatty Acids.

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The Production of Sodium Hydride and Some of its Reactions

Cited by 19 publications

References 0 publications

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine1

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine1

High Molecular Weight Alkyl Amine Nitrites and Hydrohalides1

Reactions of the Hydrocarbon Chain of Fatty Acids.

Contact Info

Product

Resources

About

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine¹

The Chemistry of Metal Carbonyls. III. The Reaction between Dicobalt Octacarbonyl and Dimethylamine¹

High Molecular Weight Alkyl Amine Nitrites and Hydrohalides¹