The preparation of α-hydroxyorganosilanes from α-borylorganosilane intermediates [1]

Larson, Gerald L.; Argülles, Rafael; Rosario, Osvaldo; SANDOVAL, S.

doi:10.1016/s0022-328x(00)84658-6

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1981

2010

Publication Types

Select...

Other4

Article2

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 18 publications

(1 citation statement)

References 15 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It is possible to obtain only monohomologated compounds using (chloromethyl)lithium or (bromomethyl)lithium generated in the presence of a boronic ester or using (dichloromethyl)lithium followed by in situ reduction with potassium triisopropoxyborohydride . Monohomologation is also obtained when halo(trialkylsilyl)methyllithium is reacted with an organoborane or a boronate . After removal of the trialkylsilyl moiety, a homologated boron compound is then obtained, which can be converted to the corresponding alcohol.…”

mentioning

confidence: 99%