The Preparation of Polymerizable Silanes Containing Organometallic Substituents in the Side-Chains

Seyferth, Dietmar; Rochow, Eugene G.

doi:10.1021/jo01120a016

Cited by 48 publications

(10 citation statements)

References 7 publications

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“…Thoroughly dried and deaerated solvents were used. The starting reagents, viz., (ArN) 2 MoCl 2 (DME), 7 Me 3 SiCH 2 Li, 8 Me 3 GeCH 2 Li, 8 Me 3 GeCH 2 MgCl, 9 Me 3 SnCH 2 MgCl, 9 and the (ArN) 2 Mo(CH 2 Bu t ) 2 complex (4), 1 were synthesized according to known procedures. The IR spectra were recorded on a Perkin-Elmer 577 spectrometer.…”

Section: Methodsmentioning

confidence: 99%

Synthesis and structures of silicon-, germanium-, and tin-containing imido-alkyl molybdenum complexes (ArN)2Mo(CH2EMe3)2 (E = Si, Ge, Sn)

et al. 2005

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New silicon , germanium , and tin containing imido alkyl molybdenum complexes (ArN) 2 Mo(CH 2 EMe 3 ) 2 (Ar is 2,6 diisopropylphenyl; E = Si (1), Ge (2), Sn (3)) were prepared in the crystalline state in 58-66% yields by the reactions of the (ArN) 2 MoCl 2 (DME) com plex with alkyllithium derivatives Me 3 ECH 2 Li (E = Si or Ge) or the Grignard reagents Me 3 ECH 2 MgCl (E = Ge or Sn). The structures of complexes 1-3 and the known analog (ArN) 2 Mo(CH 2 Bu t ) 2 (4) were established by X ray diffraction analysis. Complexes 1-3 were found to be isostructural. The coordination environment about the Mo atom can be described as a distorted tetrahedron. Complex 4 has a similar structure. The Mo-C distance tends to decrease with increasing electron donating ability of the EMe 3 group.

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Section: Methodsmentioning

confidence: 99%

Synthesis and structures of silicon-, germanium-, and tin-containing imido-alkyl molybdenum complexes (ArN)2Mo(CH2EMe3)2 (E = Si, Ge, Sn)

et al. 2005

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“…The solvents were thoroughly dried and degassed. Compounds (ArN) 2 WCl 2 (dme) [1], Me 3 ECH 2 Li (E = Si, Ge) [7], Me 3 ECH 2 MgCl (E = Ge, Sn) [8] were prepared according to the literature procedure. Infrared spectra were recorded with a ''Perkin-Elmer-577'' spectrometer.…”

Section: Generalmentioning

confidence: 99%

Synthesis and structures of silicon-, germanium- and tin-containing tungsten imido alkyl complexes (ArN)2W(CH2EMe3)2 (E=Si, Ge, Sn)

Bochkarev

Scherbakov

Malysheva

et al. 2006

Journal of Organometallic Chemistry

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“…Side chain Grignard or organolithium reagents. Organogermanium compounds with magnesium (25,99,196) or lithium (25,46) on the side chain have been prepared. The preparation followed the procedures ordinarily used in the synthesis of Grignard or organolithium reagents.…”

Section: Germolesmentioning

confidence: 99%

“…(CH3)3GeCH2MgCl reacts with CH3Si(OCH3)2 in ether after 15-hr. reflux to give (CH3)3GeCH2Si-(CH,)(OCH3)2in 75% yield (196). 13.…”

Section: N Organogermylmetallic Compounds Preparationmentioning

confidence: 99%

Organogermanium Chemistry.

Quane¹,

Bottei²

1963

Chem. Rev.

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The Preparation of Polymerizable Silanes Containing Organometallic Substituents in the Side-Chains

Cited by 48 publications

References 7 publications

Synthesis and structures of silicon-, germanium-, and tin-containing imido-alkyl molybdenum complexes (ArN)2Mo(CH2EMe3)2 (E = Si, Ge, Sn)

Synthesis and structures of silicon-, germanium-, and tin-containing imido-alkyl molybdenum complexes (ArN)2Mo(CH2EMe3)2 (E = Si, Ge, Sn)

Synthesis and structures of silicon-, germanium- and tin-containing tungsten imido alkyl complexes (ArN)2W(CH2EMe3)2 (E=Si, Ge, Sn)

Organogermanium Chemistry.

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