The Preparation of Alicyclic Trioximes

Batesky, Donald C.; Moon, Neil S.

doi:10.1021/jo01093a017

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1962

1997

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“…A trioxime, 5-methyl-1,2,3-cyclol~exanetrionetrioxine, has been prepared recently (7) and, in preliminary' studies, appeared t o possess inany of the selective properties of similar vic-dioximes. However, the presence of the third oxime group malces possible the existence of four isomers: the three hydroxy groups can be oriented so t h a t they are all amphi, two are syn, and the third either anti or amphi t o the common central group, and two are anti and the third group amphi.…”

Section: Introductionmentioning

confidence: 99%

5-METHYL-1,2,3-CYCLOHEXANETRIONETRIOXIME: A COMPARATIVE STUDY WITH SOME vic-DIOXIMES

Haines¹,

Ryan²,

Cheney³

1962

Can. J. Chem.

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A comparative study has been made of 5-methyl-1,2,3-cyclohexanetrionetrioxime with nioxime and din~ethylglyoxime; complexes with nickel, copper, and cobalt have been investigated. Dissociation constants of the three reagents, in aqueous solution, have been determined and formation constants of their copper complexes evaluated. Spectrophotornetric and potentiometric studies were used to obtain the results.

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Section: Introductionmentioning

confidence: 99%