The Preparation and Preliminary Characterisation of Eight Geological MPI‐DING Reference Glasses for In‐Situ Microanalysis

Jochum, Klaus Peter; Dingwell, Donald B.; Rocholl, Alexander; Stoll, Brigitte; Hofmann, Albrecht W.; Becker, Stefan; Besmehn, Astrid; Bessette, D.; Dietze, H.-J.; Dulski, Peter; Erzinger, J.; Hellebrand, E.; Hoppe, P.; Horn, I.; Janssens, Koen; Jenner, George A.; Klein, Marlène; McDonough, William F.; Maetz, M.; Mezger, Klaus; Müker, C.; Nikogosian, I.; Pickhardt, Carola; Raczek, Ingrid; Rhede, Dieter; Seufert, H.; Симакин, С. Г.; Sobolev, Alexander V.; Spettel, B.; Straub, Susanne M.; Vincze, László; Wallianos, A.; Weckwerth, G.; Weyer, Stefan; Wolf, Dietlinde; Zimmer, Martin

doi:10.1111/j.1751-908x.2000.tb00590.x

Cited by 313 publications

(283 citation statements)

References 43 publications

(36 reference statements)

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“…They mainly include USGS reference glasses (BCR-2G, BHVO-2G and BIR-1G), MPI-DING reference glasses (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, ATHO-G and T1-G) and Chinese Geological Standard Glasses (CGSG) (CGSG-1, CGSG-2, CGSG-4 and CGSG-5). The USGS reference glasses have natural basaltic compositions [27,[58][59][60], whereas the MPI-DING reference glasses comprise basalt (KL2-G and ML3B-G), andesite (StHs6/80-G), komatiite (GOR128-G, GOR132-G), peridotite (BM90/21-G), rhyolite (ATHO-G) and quartz diorite (T1-G) [61,62], and the CGSG reference glasses comprise basalt (CGSG-1), syenite (CGSG-2), andesite (CGSG-5) and soil (CGSG-4) [63].…”

Section: Reference Materials and Matrix Effectsmentioning

confidence: 99%

Applications of LA-ICP-MS in the elemental analyses of geological samples

Liu

et al. 2013

Chin. Sci. Bull.

102

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Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), which is a rapidly developing analytical technique for the analyses of trace elements and isotopes, plays an important role in advancing the study of Earth science, especially with respect to micro-geochemistry. This article reviews the application of LA-ICP-MS in the elemental analysis of solid geological samples. Although LA-ICP-MS has been widely used in the spatial resolution analysis of element compositions and rapid bulk analysis of whole-rock and soil samples, the analysis accuracy is restricted by numerous factors, including the instrumental conditions, the elemental fractionation and matrix effects, the lack of sufficient matrix-matched reference materials, and the strategies for quantitative calibration and sensitivity drift correction. According to the type of samples and the analyte elements, the analysis accuracy can be improved through the optimization of instrument conditions and the adoption of suitable correction strategies and reference materials. LA-ICP-MS, geological sample, elemental analysis, quantitative strategy Citation:Liu Y S, Hu Z C, Li M, et al. Applications of LA-ICP-MS in the elemental analyses of geological samples.

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Section: Reference Materials and Matrix Effectsmentioning

confidence: 99%

Applications of LA-ICP-MS in the elemental analyses of geological samples

Liu

et al. 2013

Chin. Sci. Bull.

102

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“…Trace element contents in the tests were quantified by fundamental parameters using PyMCA 4.2.2 (Solé et al, 2007). The fundamental parameter calculations were recalibrated for trace element calibration purposes by using a pressed calcite pellet (containing 756 µg/g Cr and 727 µg/g As) and the MPI-DING reference glass StHS6/80-G standard (Max-Planck-Institut für Chemie, Germany) (Jochum et al, 2000) as primary standards. Geometry effects caused by the uneven shape of the tests were corrected by calculating the absorption of the incoming beam from the count rate of the primary monitor (in front of the sample) and the secondary monitor (behind the sample).…”

Section: µ-Synchrotron Xrfmentioning

confidence: 99%

Heavy metal incorporation in foraminiferal calcite: results from multi-element enrichment culture experiments with <i>Ammonia tepida</i>

et al. 2010

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Abstract. The incorporation of heavy metals into carbonate tests of the shallow water benthic foraminifer Ammonia tepida was investigated under controlled laboratory conditions. Temperature, salinity, and pH of the culture solutions were kept constant throughout the duration of this experiment, while trace metal concentrations were varied. Concentrations of Ni, Cu, and Mn were set 5-, 10-, and 20 times higher than levels found in natural North Sea water; for reference, a control experiment with pure filtered natural North Sea water was also analysed. The concentrations of Cu and Ni from newly grown chambers were determined by means of both µ-synchrotron XRF and Laser Ablation Inductively Coupled Plasma Mass Spectroscopy (LA-ICP-MS). The results of both independent analytical techniques agreed within the analytical uncertainty. In general, the concentration of the analysed elements in the tests increased in line with their concentration in the culture solutions. Potential toxic and/or chemical competition effects might have resulted in the decreased incorporation of Ni and Cu into the calcite of the specimens exposed to the highest elemental concentrations. Mn incorporation exhibited large variability in the experiment with the 20-fold increased element concentrations, potentially due to antagonistic effects with Cu. The partition coefficients of Cu and Ni were calculated to be 0.14 ± 0.02 and 1.0 ± 0.5, respectively, whereas the partition coefficient of Mn was estimated to be least 2.4. These partition coefficients now open the way for reconstructing past concentrations for these elements in sea water.

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“…The standard was analyzed after every 10-15 sample measurements. To ensure accuracy and precision, we used natural basaltic glass standard KL2 (Jochum et al 2000), which was measured after every 4-5 measurements (electronic supplement eTable 4).…”

Section: Simentioning

confidence: 99%

Volatile (S, Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc

Churikova

Wörner²,

Mironov

et al. 2007

Contrib Mineral Petrol

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Volatile element, major and trace element compositions were measured in glass inclusions in olivine from samples across the Kamchatka arc. Glasses were analyzed in reheated melt inclusions by electron microprobe for major elements, S and Cl, trace elements and F were determined by SIMS. Volatile element-trace element ratios correlated with fluid-mobile elements (B, Li) suggesting successive changes and three distinct fluid compositions with increasing slab depth. The Eastern Volcanic arc Front (EVF) was dominated by fluid highly enriched in B, Cl and chalcophile elements and also LILE (U, Th, Ba, Pb), F, S and LREE (La, Ce). This arc-front fluid contributed less to magmas from the central volcanic zone and was not involved in back arc magmatism. The Central Kamchatka Depression (CKD) was dominated by a second fluid enriched in S and U, showing the highest S/K 2 O and U/Th ratios. Additionally this fluid was unusually enriched in 87 Sr and 18 O. In the back arc Sredinny Ridge (SR) a third fluid was observed, highly enriched in F, Li, and Be as well as LILE and LREE. We argue from the decoupling of B and Li that dehydration of different water-rich minerals at different depths explains the presence of different fluids across the Kamchatka arc. In the arc front, fluids were derived from amphibole and serpentine dehydration and probably were water-rich, low in silica and high in B, LILE, sulfur and chlorine. Large amounts of water produced high degrees of melting below the EVF and CKD. Fluids below the CKD were released at a depth between 100 and 200 km due to dehydration of lawsonite and phengite and probably were poorer in water and richer in silica. Fluids released at high pressure conditions below the back arc (SR) probably were much denser and dissolved significant amounts of silicate minerals, and potentially carried high amounts of LILE and HFSE.

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The Preparation and Preliminary Characterisation of Eight Geological MPI‐DING Reference Glasses for In‐Situ Microanalysis

Cited by 313 publications

References 43 publications

Applications of LA-ICP-MS in the elemental analyses of geological samples

Applications of LA-ICP-MS in the elemental analyses of geological samples

Heavy metal incorporation in foraminiferal calcite: results from multi-element enrichment culture experiments with <i>Ammonia tepida</i>

Volatile (S, Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc

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The Preparation and Preliminary Characterisation of Eight Geological MPI‐DING Reference Glasses for In‐Situ Microanalysis

Cited by 313 publications

References 43 publications

Applications of LA-ICP-MS in the elemental analyses of geological samples

Applications of LA-ICP-MS in the elemental analyses of geological samples

Heavy metal incorporation in foraminiferal calcite: results from multi-element enrichment culture experiments with &lt;i&gt;Ammonia tepida&lt;/i&gt;

Volatile (S, Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc

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Heavy metal incorporation in foraminiferal calcite: results from multi-element enrichment culture experiments with <i>Ammonia tepida</i>