1934
DOI: 10.1021/ja01318a015
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The Potentiometric Determination of Arsenates1

Abstract: The Potentiometric Determination of Arsenates 577 water and alcohol. The velocities increase in the orders given.2. The decompositions in water, and the decomposition of the sodium salt in alcohol, follow the first order law, but the decompositions of the anilinium salt in aniline and alcohol, and of the barium salt in alcohol, show an increase in the specific reaction rate as the decomposition proceeds. These departures have been explained on the basis of changes in the degree of ionization.3. The reaction ve… Show more

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Cited by 3 publications
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“…Spychalski(543) titrated Bredig solution for silver with bromide or iodide with an accuracy of 0.5 to 1 per cent of the silver present.Hiltner and Gittel (234) developed a systematic potentiometric scheme for estimation of silver, bismuth, lead, copper, and cadmium in the same solution.Silver nitrate as reagent. Arsenate, in acetate buffer plus alcohol(Hanson et al,221; Spacu,537) Azide (Moskovich, 386; lead azide in 2 per cent barium nitrate solution, 0.04 N in nitric acid, and buffered with 0.2 N…”
mentioning
confidence: 99%
“…Spychalski(543) titrated Bredig solution for silver with bromide or iodide with an accuracy of 0.5 to 1 per cent of the silver present.Hiltner and Gittel (234) developed a systematic potentiometric scheme for estimation of silver, bismuth, lead, copper, and cadmium in the same solution.Silver nitrate as reagent. Arsenate, in acetate buffer plus alcohol(Hanson et al,221; Spacu,537) Azide (Moskovich, 386; lead azide in 2 per cent barium nitrate solution, 0.04 N in nitric acid, and buffered with 0.2 N…”
mentioning
confidence: 99%