The Politics of Remembering the GDR

Beattie, Andrew

doi:10.1057/9780230349698.0007

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“…The lifetime of XeClz in the first two cases is extremely short, and in the third case, the stability of XeC12 could be due to matrix or cage effects of the dielectric medium. 4 Neither the geometry nor the dissociation energy of gas-phase molecular XeC12 (if it is stable) is known. However, XeC12 is well-known as a T-shaped van der Waals complex.…”

Section: Introductionmentioning

confidence: 99%

The potential energy surface of xenon dichloride

Richardson¹,

Hall²

1993

J. Phys. Chem.

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Multireference configuration-interaction calculations with the Davidson size-consistency correction are used to calculate the potential energy surface of XeC12. The van der Waals complex is found to be the most stable species. The linear XeClz molecule is bound by 8.0 kcal/mol relative to the dissociated atoms, but is at least 38 kcal/mol less stable than the van der Waals complex. In addition, no stable triangular intermediate is found to exist at this level of calculation.

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Section: Introductionmentioning

confidence: 99%