The poisonous truth about the mercury drop test: the effect of elemental mercury on Pd(0) and Pd(II)ArX intermediates
Ian Chagunda,
Tiago Fisher,
Makenna Schierling
et al.
Abstract:The mercury drop test is a widely used method for distinguishing between homogeneous and heterogeneous catalysis in organometallic systems. However, recent research has highlighted the limitations of this test due to the intrinsic reactivity of some organometallic compounds towards elemental mercury. In this study, we used real-time mass spectrometry with charge-tagged substrates to investigate the effect of elemental mercury on LnPd0 and PdIIArX intermediates common in palladium-catalysed cross-coupling react… Show more
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