“…2a). Here, the exothermic peaks are denoted by T p1 , T p2 , T p3 and T p4 , it is found that the temperature interval between T p1 and T p2 increases with c Zr , suggesting that Zr can restricts the eutectic crystallization of the amorphous ribbon, which is similar to the effect of Cu and Ni in Fe 73.5 Nb 3 Cu 1 Si 13.5 B 9 glassy alloy [19]. In addition, a slight endothermic bump before the first exothermic peak can be seen in the DSC curves, which is also visible in the DSC curves with heating rates of 20, 30 and 40 K/min (not shown in this paper).…”