1985
DOI: 10.1063/1.865373
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The paradox of the inverted temperature profiles between an evaporating and a condensing surface

Abstract: The effect of internal degrees of freedom and of a class of boundary conditions on inverted temperature profiles between evaporating and condensing parallel plates is considered. It is found that such inverted profiles are present also in the case of polyatomic species and for most (but not all) modifications of the boundary conditions.

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Cited by 50 publications
(19 citation statements)
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“…2, the temperature jump increases with the increase in the liquid temperature difference in the both cases of the normalized reference liquid temperature; this increase in the temperature jump is related to the increase in the velocity in the direction normal to the kinetic boundary [40]. Furthermore, in this system consisting of two liquid slabs at different temperatures, wellknown characteristic phenomenon inverted temperature gradient [8,41,42,43,44] occurs in the bulk vapor as a consequence of the temperature jump. We verified the occurrence of the inverted temperature gradient by using the EV-DSMC simulation.…”
Section: Macroscopic Variables Obtained From the Ev-dsmc Simulationsmentioning
confidence: 99%
“…2, the temperature jump increases with the increase in the liquid temperature difference in the both cases of the normalized reference liquid temperature; this increase in the temperature jump is related to the increase in the velocity in the direction normal to the kinetic boundary [40]. Furthermore, in this system consisting of two liquid slabs at different temperatures, wellknown characteristic phenomenon inverted temperature gradient [8,41,42,43,44] occurs in the bulk vapor as a consequence of the temperature jump. We verified the occurrence of the inverted temperature gradient by using the EV-DSMC simulation.…”
Section: Macroscopic Variables Obtained From the Ev-dsmc Simulationsmentioning
confidence: 99%
“…The investigation of the dynamics of a gas during evaporation and condensation is a classical problem of the kinetic theory of gases [2], there has been a huge number of papers solving the full Boltzmann equation or an appropriate model equation. With a few exceptions [5], very little has been said about the boundary conditions at the interphase and their influence on the solution of the Boltzmann equation governing the gas phase. The usual approach is to assume a Maxwellian distribution for the evaporated molecules and diffuse or specular reflection, or a combination, for the reflected molecules.…”
Section: Introductionmentioning
confidence: 99%
“…4 All those calculations were for a unity condensation coefficient. Cercignani et al 5 used the moment method with nonunity condensation coefficient and specular reflection, but the criterion for the inverted temperature gradient did not change much when the condensation coefficient was varied from 0 to 1. However, Ytrehus 6 reached a different conclusion.…”
mentioning
confidence: 98%