2009
DOI: 10.1016/j.gca.2009.08.033
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The origin of refractory minerals in comet 81P/Wild 2

Abstract: Refractory Ti-bearing minerals in the calcium-, aluminum-rich inclusion (CAI) Inti, recovered from the comet 81P/Wild 2 sample, were examined using analytical (scanning) transmission electron microscopy (STEM) methods including imaging, nanodiffraction, energy-dispersive spectroscopy (EDX) and electron energy loss spectroscopy (EELS). Inti fassaite (Ca(Mg,Ti,Al) (Si,Al) 2 O 6 ) was found to have a Ti 3+ /Ti 4+ ratio of 2.0 ± 0.2, consistent with fassaite in other solar system CAIs. The oxygen fugacity (log f O… Show more

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Cited by 35 publications
(21 citation statements)
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“…The spectrum of the Inti pyroxene is remarkably similar to that of the Allende reference material. Thus, the EELS results (Chi 2008;Chi et al, Forthcoming) show that Inti Ti-rich pyroxene has a significant Ti 3+ component, probably well within the range of fassaite from Allende. The presence of Ti 3+ in Inti tpx is also indicated by low cation totals (per six oxygen anions), with all Ti reported as Ti 4+ , as in the analyses shown in Table 3.…”
Section: Clinopyroxenementioning
confidence: 89%
“…The spectrum of the Inti pyroxene is remarkably similar to that of the Allende reference material. Thus, the EELS results (Chi 2008;Chi et al, Forthcoming) show that Inti Ti-rich pyroxene has a significant Ti 3+ component, probably well within the range of fassaite from Allende. The presence of Ti 3+ in Inti tpx is also indicated by low cation totals (per six oxygen anions), with all Ti reported as Ti 4+ , as in the analyses shown in Table 3.…”
Section: Clinopyroxenementioning
confidence: 89%
“…These minerals can form only at temperatures on the order of thousands of kelvins, but they are found in comets (Campins & Ryan 1989;Wooden et al 2005;Chi et al 2009;Kelley & Wooden 2009). How the high temperature minerals got to the cold region where comets form is a classic problem.…”
Section: Implications For Cometsmentioning
confidence: 99%
“…Terminal particles correspond to the best-studied Stardust material until now. They are made of coarse grains, including CAI-like or chondrule-like assemblages Leroux et al, 2008a;Nakamura et al, 2008;Simon et al, 2008;Chi et al, 2009;Jacob et al, 2009a). With SXRF data taken from seven Stardust tracks, Lanzirotti et al (2008) showed that the quantity of material (based on the iron mass) contained within the terminal particles is variable, from 10% to 80% depending on the track morphology.…”
Section: Introductionmentioning
confidence: 99%