The Optical properties of Fe-Doped TiO2 films prepared by Hydrothermal Technique

Abstract

TiO 2 films doped with Fe at (0.1, 0.3, 0.7, 1.5 at %) were successfully deposited on the fluorine doped tin oxide (FTO)-glass substrate using hydrothermal technique. X-Ray Diffraction (XRD) analysis showed that the only phase obtained of TiO 2 is rutile. Moreover, the crystallinity did not have remarkable change after doping. Ultra violet-visible (UV-vis) spectroscopy analysis show that the energy band gap value (E g) decreases slightly with the increase of the doping concentration from 0.1 to 0.3 at%. The reflectivity measurements in general gave identical results but with higher values of E g. Urbach energy for doping concentrations 0.7 and 1.5 at % is quite high and in the range 1-2 eV.

Effect of Growth Time on the Structural, Optical and Electrical Properties of the 1%Fe doped TiO2 p-type Synthesized by Hydrothermal Technique

“…20 mL of the mixture is charged to a homemade stainless-steel autoclave (30 mL). A schematic diagram for the autoclave is presented in [7]. The autoclave was put inside an electric oven.…”