We study the short-range nucleon-nucleon interaction in a nonrelativistic chiral constituent quark model by diagonalizing a Hamiltonian containing a linear confinement and a Goldstone boson exchange interaction between quarks. A finite six-quark basis obtained from single particle cluster model states was previously used. Here we show that the configurations which appear naturally through the use of molecular orbitals, instead of cluster model states, are much more efficient in lowering the six-quark energy.Constituent quark models have been applied to the study of the nucleonnucleon interaction. The Hamiltonian of such models usually contains a kinetic term, a confinement term and an effective one-gluon exchange (OGE) term. These models explain the short-range repulsion in the N N systems as due to the colour-magnetic part of the OGE interaction combined with quark interchanges between the 3q clusters. Nevertheless, an effective mesonexchange potential, introduced through the coupling of mesons to 3q cluster collectively, is required in order to reproduce the intermediate-and long-range attraction. Another category are the hybrid models. There, in addition to OGE interaction, the quarks belonging to different 3q clusters interact via pseudoscalar and scalar meson exchange. In these models the short-range repulsion in the N N system is still attributed to the OGE interaction between the constituent quarks. The medium-and the long-range attraction are due to meson-exchange, as expected.In a recent exploratory work 1 , by using the Born-Oppenheimer approximation, we calculated an effective N N interaction at zero separation distance, within the constituent quark model 2,3,4 . In this model the quarks interact via Goldstone boson exchange (GBE) instead of OGE of conventional models, and the hyperfine splitting in hadrons is obtained from the short-range part of the GBE interaction. An important merit of the GBE model is that it reproduces the correct order of positive and negative parity states in both nonstrange 3 and strange baryons 4 . In Ref. 1 we showed that the same short-range part of the GBE interaction, also induces a short-range repulsion in the N N system.In Ref. 1 the height of the repulsive core was about 800 MeV for the 3 S 1 channel and 1300 MeV for the 1 S 0 channel. Such a result has been obtained from diagonalizing the Hamiltonian of Ref. 3 in a six-quark cluster model 1