The molecular Zeeman effect in F12C15N

Rock, S. L.; McGurk, J. C.; Flygare, W. H.

doi:10.1016/0009-2614(73)85042-0

Cited by 15 publications

(2 citation statements)

References 15 publications

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“…The financial support of the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie is gratefully acknowledged. ** From rotational Zeeman effect studies, the molecular quadrupole moments of OCS (normal isotope) and FC 15 N were determined to be Q(OCS) = (-0.88±0.15) X 10-26 esu em 2 [32] and Q(FCN) = (-3.7 ± 1.0) X 10 -26 esu cm 2 [33]. …”

Section: Acknowledgementsmentioning

confidence: 99%

Investigation of Self-and Foreign Gas Collision-induced Transitions between M-resolved Rotational Levels of OCS

Mäder

1982

Zeitschrift Für Naturforschung A

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Four-level MW-MW double resonance experiments on rotational Stark levels j = 0, 1, 2 and 3 of OCS have been performed to investigate transfer of rotational energy by collisions of OCS with OCS, He, Ne, Ar, Kr, H2, N2, O2, and CH3F. Theoretical arguments are given for the interpretation of the experimentally determined ^-values by considering Bloch-type equations of an "embedded" four-level system with ±M degeneracy of the energy levels. The results indicate significant deviations from first order dipole collisional interaction.

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Section: Acknowledgementsmentioning

confidence: 99%

Investigation of Self-and Foreign Gas Collision-induced Transitions between M-resolved Rotational Levels of OCS

Mäder

1982

Zeitschrift Für Naturforschung A

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“…This tendency of electron density to spread to the ends of the molecule is also apparent when discussing the change in sign of the quadrupole moments of FCN and HCN. 28 The Atlas Computer Laboratory is thanked for the provision of computer time.…”

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confidence: 99%

Use of partial (and full) Löwdin integral approximations in molecular orbital calculations on HCN and FCN

Dixon¹,

Doggett²,

Howat³

1975

J. Chem. Soc., Faraday Trans. 2

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Tests and applications of the PLA and FLA integral approximation methods are made by calculating a wide range of molecular properties for HCN using a basis of single-zeta atomic orbitals. A comparison of the results with those obtained from an ab initio calculation establishes the PLA method as the better of the two approximation methods. The molecular orbitals for HCN and FCN are then determined for five different X-C separations (using a double-zeta basis set), and the changes in the electron distribution of each molecule are discussed with the aid of appropriate electron density maps, as well as population analyses related to a basis of natural hybrids.

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36wil - 77mal1

Demaison¹

Landolt-Börnstein - Group II Molecules and Radicals

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The molecular Zeeman effect in F12C15N

Cited by 15 publications

References 15 publications

Investigation of Self-and Foreign Gas Collision-induced Transitions between M-resolved Rotational Levels of OCS

Investigation of Self-and Foreign Gas Collision-induced Transitions between M-resolved Rotational Levels of OCS

Use of partial (and full) Löwdin integral approximations in molecular orbital calculations on HCN and FCN

36wil - 77mal1

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