The Mobility of the Hydride Hydrogen Atom in Trialkyltin, ‐germanium, and ‐silicon Hydrides

Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond Activation of Hydrostannanes

“…As for the hydrosilane activation, [ 5b ] + [BAr F 4 ] − promoted 1 H/ 2 H scrambling between n Bu 3 SnD ( 2a - d 1 ) and Et 3 SnH ( 2b ). In our hands, no deuterium exchange occurred in the absence of the catalyst at 30 °C (see the Supporting Information for details).…”