1976
DOI: 10.1070/pu1976v019n12abeh005375
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The Metal-Dielectric Transition in Liquid Metals and Semiconductors at High Temperatures and Pressures in the Region of the Critical Point

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“…With increasing temperature, the chain length becomes short [1,2], electrical conductivity increases [3] and the optical gap decreases [4]. It is known that further increase of temperature with application of pressure gives rise to the semiconductor-metal transition near the liquid-gas critical point (T c = 1615 • C, P c = 385 bar, ρ c = 1.85 g cm −3 [5]) [6][7][8][9][10][11]. NMR study [2] revealed that the chain molecule contains about ten atoms on average when the semiconductor-metal transition occurs.…”
Section: Introductionmentioning
confidence: 99%
“…With increasing temperature, the chain length becomes short [1,2], electrical conductivity increases [3] and the optical gap decreases [4]. It is known that further increase of temperature with application of pressure gives rise to the semiconductor-metal transition near the liquid-gas critical point (T c = 1615 • C, P c = 385 bar, ρ c = 1.85 g cm −3 [5]) [6][7][8][9][10][11]. NMR study [2] revealed that the chain molecule contains about ten atoms on average when the semiconductor-metal transition occurs.…”
Section: Introductionmentioning
confidence: 99%