“…[18][19][20][29][30][31][32][33][34] These catalyst include the ions of Cu [29][30][31]34], Ag [18][19][20][32][33][34] and Fe [34]. In addition, a number of organic substrates were studied, including alcohols, aldehydes, and ethers.…”
Section: E Transition Metal Catalystsmentioning
confidence: 99%
“…Previous work on the effect of transition metal catalysts on the rate of oxidation of organic substrates by peroxydisulfate [18][19][20][29][30][31][32][33][34] focused primarily on the decomposition of the peroxydisulfate, and not on the mineralization of the organic. For the work detailed in this report, it was felt that a more realistic approach with regard to waste treatment by DCO was to measure the overall Destruction and Removal Efficiencies (DRE's) on a matrix of catalysts, temperatures, and organic substrates.…”
“…[18][19][20][29][30][31][32][33][34] These catalyst include the ions of Cu [29][30][31]34], Ag [18][19][20][32][33][34] and Fe [34]. In addition, a number of organic substrates were studied, including alcohols, aldehydes, and ethers.…”
Section: E Transition Metal Catalystsmentioning
confidence: 99%
“…Previous work on the effect of transition metal catalysts on the rate of oxidation of organic substrates by peroxydisulfate [18][19][20][29][30][31][32][33][34] focused primarily on the decomposition of the peroxydisulfate, and not on the mineralization of the organic. For the work detailed in this report, it was felt that a more realistic approach with regard to waste treatment by DCO was to measure the overall Destruction and Removal Efficiencies (DRE's) on a matrix of catalysts, temperatures, and organic substrates.…”
“…Previous work on the effect of transition metal catalysts on the rate of oxidation of organic substrates by peroxydisulfate [l&20, [29][30][31][32][33][34] focused primarily on the decomposition of the peroxydisulfate, and not on the mineralization of the organic. For the current work, it was felt that a more.…”
Section: Resultsmentioning
confidence: 99%
“…This has been noted before in the literature. [l&20, [29][30][31][32][33][34] The above results lead to the conclusion that catalysis of organic destmction by peroxydisulfate is merely due to the formation of another, favorably solvated transition metal cation with a high oxidation potential.…”
Section: Discussionmentioning
confidence: 99%
“…[18][19][20] These catalysts include the ions of Cu [29][30][31]341, Ag [18][19][20] and Fe [34]. In addition, a number of organic substrates were studied, including alcohols, aldehydes, and ethers.…”
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