1937
DOI: 10.1021/ja01290a079
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The Measurement of the Molal Ferric-Ferrous Electrode Potential

Abstract: this determination exceeded 99.99 mole per cent. been determined and the observed value for the The phase equilibrium diagram for the con-eutectic point was -160.2 f 0.5'. densed system 2-methylpentane-n-heptane has NORWOOD, PENNA.

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Cited by 39 publications
(20 citation statements)
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“…Ici par contre, le ClO2 est un produit de la reaction globale et [9] est un quasiCquilibre. On retrouve la loi [5] [I21 HCIOz + C1 + HClO + CIO La rupture peut Ctre [I31 ou [14] D'autre part nous savons (1) que le HCIO form6 rtagit trks rapidement avec le chlorite suivant [15] et [16].…”
Section: Interpretation Des Resultatsunclassified
See 1 more Smart Citation
“…Ici par contre, le ClO2 est un produit de la reaction globale et [9] est un quasiCquilibre. On retrouve la loi [5] [I21 HCIOz + C1 + HClO + CIO La rupture peut Ctre [I31 ou [14] D'autre part nous savons (1) que le HCIO form6 rtagit trks rapidement avec le chlorite suivant [15] et [16].…”
Section: Interpretation Des Resultatsunclassified
“…Avec [14], du fait de la prtpondtrance de [15] par rapport a [16], on prevoit une formation relative de CIOz beaucoup plus importante que celle obt'enue expCrimentalement pour la reaction catalyste par le fer. Nous admettons donc que, dans nos conditions, la rupture est [13].…”
Section: Interpretation Des Resultatsunclassified
“…50 In the determination of the standard potential of highly charged cations such as Fe 3+ , obtaining accurate extrapolations to infinite dilution requires additional corrections for chemical effects such as hydrolysis of a first-shell water molecule coordinated to the Fe 3+ ion, as well as accounting for non-unit activity coefficients of Fe 3+ , Fe 2+ , and H + under measurement conditions. 51 Most aqueous experimental reduction potentials have been extrapolated to infinite dilution and therefore these may be directly compared with theoretical calculations in which activity effects are ignored by assuming infinite dilution.…”
Section: Definition Of the Standard Reduction Potentialmentioning
confidence: 99%
“…where E 0 Fe 3þ !Fe 2þ ¼ 0:77V is the standard reduction potential of Fe 3+ (Schumb et al, 1937) and K i is the stability constant of the complex i.…”
Section: Evaluation Of Rate Constants In the Context Of Marcus Theorymentioning
confidence: 99%