We measure the nonlinear refractive index coefficients in N 2 , O 2 and Ar from visible through mid-infrared wavelengths ( = 0.4 2.4 µm). The wavelengths investigated correspond to transparency windows in the atmosphere. Good agreement is found with theoretical models of (3) . Our results are essential for accurately simulating the propagation of ultrashort mid-IR pulses in the atmosphere.Filamentary propagation of intense ultrashort laser pulses in atmosphere for < ~1 m has been a subject of extensive study [1,2], finding applications in the generation of terahertz radiation [3], high harmonic generation [4], air lasing [5][6][7], and remote inscription of optical waveguides into air [813]. It has been anticipated that new regimes of laser filamentation are possible at longer wavelengths, such as in the midinfrared (mid-IR, ~ 1.5-10 m), where beam collapse arrest may occur through harmonic walk-off rather than plasma-induced refraction [14]. Mid-IR filamentation is effective for generating coherent keV-level photon beams in high pressure gas-filled capillaries [15] and broad mid-IR supercontinua in high pressure gas volumes [16].Accurate values for nonlinear coefficients are essential for high fidelity simulations of intense laser propagation [17]-such simulations are indispensable not only for designing experiments and informing applications, but they also motivate the design and parameters of the lasers themselves. We recently showed that in the near-infrared (pump wavelength e = 0.8 µm), air propagation simulations depend very sensitively on the values used for the coefficients (n2) describing the instantaneous electronic nonlinear response of air constituents [18]. Best agreement of the simulations with axially resolved measurements occurs for n2 coefficients measured in [19].In this Article, we present measurements of n2 for the air constituents N2, O2 and Ar at pump wavelengths ranging from 400 nm to 2400 nm. The near through mid-IR wavelengths chosen (e = 1250 nm, 1650 nm, 2200 nm, 2400 nm) are within the transparency windows of air [20]. We find that the nonlinear response is quite dispersionless over the range of wavelengths investigated, except near e=400 nm, consistent with a simple model for the third-order nonlinear susceptibility developed by Bishop [21].The experimental setup is shown in Fig 1. Pulses from a 1 kHz Ti:Sapphire regenerative amplifier centered at 800 nm are split, with 2.8 mJ pumping an optical parametric amplifier (OPA) [22], which is tunable from 1100 nm to 2600 nm. A chopper reduces the pulse repetition rate to 500 Hz. The remaining portion of the 800 nm pulse is attenuated and weakly focused in a 2 atm xenon gas cell, where filamentation generates a =500700 nm broadband supercontinuum (SC) transmitted through the pump-rejecting dichroic splitter. A Michelson interferometer splits the SC into two collinear pulses (reference and probe) temporally separated by 2 ps. The dispersive glass in the SC beam path introduces equal positive chirp to ~1.5 ps on the reference ...