The mass spectral analysis of several hydrazine derivatives

Abstract

The mass spectral analysis of 17 hydrazine derivatives of the type -2-(carboxypropionyl)-(nine compounds) and -2-(carboxyacryloyl)-(eight compounds) under electron impact is reported. The fragmentation has been rationalized from the exact mass measurements as well as the detection of metastable transitions. #

Determination of novel aromatic amines in environmental samples by gas chromatography/mass spectrometry

“…The ion d is probably stabilized by participation of the C atom from the radical site to expansion of the aromatic ring, as has also been reported earlier 27,. 38…”

“…Fragmentation reactions involving 1H or 2H atom transfers, for nitrogen‐containing compounds, have been extensively studied 26,. 30,, 38 The ions a 31 , a 32 and a 34 are characteristic of the A 3 group, and are observable for compound 16 (quantitatively the major compound of this group). For the group A 4 , the ions a 41 , a 42 and a 44 are characteristic, and observable for all compounds of this group (compounds 18 – 20 ).…”