1973
DOI: 10.1088/0022-3700/6/10/030
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The M4,5spectrum of58Ce and the γ-α phase transition

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Cited by 16 publications
(3 citation statements)
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“…The variation of valence between the two phases is less than 0.03. We cannot exclude the formation of an oxide layer on the metallic cerium during the few minutes needed to transfer the sample into the chamber, but the value of v f is in good agreement with the 57% of Ce 3+ found previously in the α phase on an in-situ evaporated cerium film40. The absence of valence variation is in agreement with Compton scattering experiments31.…”
Section: Resultssupporting
confidence: 87%
“…The variation of valence between the two phases is less than 0.03. We cannot exclude the formation of an oxide layer on the metallic cerium during the few minutes needed to transfer the sample into the chamber, but the value of v f is in good agreement with the 57% of Ce 3+ found previously in the α phase on an in-situ evaporated cerium film40. The absence of valence variation is in agreement with Compton scattering experiments31.…”
Section: Resultssupporting
confidence: 87%
“…Because of the appearance of the peaks C and E in the 3d XAS spectrum of C e 0 2 , our results do not confirm the previous data reported by Ottewell et al (1973) and Bonnelle et af (1974). The data of the former authors show no sign of either C o r E, and their spectrum closely resembles that of La3+ with which Ce4+ is iso-electronic.…”
Section: Results For Cerium and Ceocontrasting
confidence: 99%
“…Therefore, acquiring single-phase samples of metals at or near this transition, such as manganese ͑four phases͒, cerium ͑four phases͒, and plutonium ͑six phases͒, is uncertain, rendering spectroscopic techniques with low spatial resolution questionable. 4 Producing large single crystals of these metals is even more difficult, and for many of them has yet to be accomplished. Rather than struggling to generate single-phase or singlecrystal samples of these complex metals, one may take the route of using an experimental technique that probes small portions of a sample, circumventing crystal growth problems.…”
mentioning
confidence: 99%