The Local and Collective Mobility in Polymer Chains and Networks with Included Rigid Particles Elastically Connected with the Network

Abstract

Summary:The theory of molecular mobility of a polymer network with included rodlike particles is developed. The case is considered when the length of rods is comparable or greater than the average distance between neighboring cross-links of the primary network. The long-scale dynamics of the network is described by means of a regular cubic ''coarse-grained'' model. The junctions of this model describe the great network fragments (domains) the sizes of which are near to the average distance between neighboring rods.The quasi-elastic interactions between rods and network fragments lead to a broad relaxation spectrum for included rods as compared with free rods which are characterized by a single relaxation time of rotational diffusion. The frequency dependence of the dielectric loss factor of included rods is calculated for rods with permanent dipole moments directed parallel to the long axes of the rods chaotically distributed in the network. The frequency dependence of dynamic modulus of a polymer network with included rods is obtained. The increment in the dynamic modulus of the relatively short network motions (smaller than the distance between rods) also is taken into account. The broad relaxation spectrum of included rods leads to appearance of several maximums on the frequency dependences of both the dielectric loss factor and dynamical modulus.

Rheology of Quaternary Ammonium Gemini Surfactant Solutions: Effects of Surfactant Concentration and Counterions

“…This condition is necessary because the molecules have to respond dramatically to applied stress by changing their conformations. In addition, high flexibility is also essential, i.e., the internal mobility with free rotations about skeletal bonds that enable the necessary molecular rearrangement not to be hampered by constraints due to inherent molecular rigidity (Gotlib, Torchinskii, Toshchevikov, & Shevelev, 2006). A coherent, multiconnected stable structure resists mechanical perturbation (Rehage & Hoffmann, 2006).…”