The Lithium-Strontium Equilibrium System

Wang, Frederick E.; Kanda, F. A.; King, Aden J.

doi:10.1021/j100817a015

Cited by 21 publications

(6 citation statements)

References 2 publications

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“…In our work, the existence of Sr 3 Li 2 and Sr 6 Li 23 has been confirmed, and a new compound that separates these phases according to an updated phase diagram Sr–Li has been discovered. We could not detect any traces of Sr 8 Li or Sr 7 Li mentioned in the previous work . Samples with these compositions contain a mixture of Sr 3 Li 2 and Sr.…”

Section: Resultscontrasting

confidence: 52%

“…We could not detect any traces of Sr 8 Li or Sr 7 Li mentioned in the previous work. 5 Samples with these compositions contain a mixture of Sr 3 A similar solid solution was also observed for mixed alkaline-earth-metal compounds containing Ba/Sr or Sr/Ca. It is known that Ca in such compounds can replace both the alkaline earth and Li.…”

Section: ■ Introductionmentioning

confidence: 58%

“…All binary compounds in these systems are restricted to light alkali-metal representatives containing Li and Na. Two compounds are known in the system Na–Ba (Na 2 Ba and NaBa), one with Ca and Li, represented by the two modifications of CaLi 2 , , two with Sr and Li (Sr 6 Li 23 and Sr 3 Li 2 ), and one with Ba and Li, namely, BaLi 4 . , In the course of our investigations, Ba 19 Li 44 was found as a second representative. Because Ba and Sr have very similar atomic radii, we decided to investigate more accurately the Sr–Li system in order to check the existence of Sr 19 Li 44 or other chemically or structurally related phases.…”

Section: Introductionmentioning

confidence: 66%

“…All binary compounds in these systems are restricted to light alkali-metal representatives containing Li and Na. Two compounds are known in the system Na−Ba (Na 2 Ba 1 and NaBa), 2 one with Ca and Li, represented by the two modifications of CaLi 2 , 3,4 two with Sr and Li (Sr 6 Li 23 5 and Sr 3 Li 2 ), 6 and one with Ba and Li, namely, BaLi 4 . 7,8 In the course of our investigations, Ba 19 Li 44 9 was found as a second representative.…”

Section: ■ Introductionmentioning

confidence: 99%

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Synthesis, Crystal Structure, and TEM Analysis of Sr₁₉Li₄₄ and Sr₃Li₂: A Reinvestigation of the Sr–Li Phase Diagram

et al. 2014

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Two intermetallic phases in the Sr-Li system have been synthesized and structurally characterized. According to single-crystal X-ray diffraction data, Sr(19)Li(44) and Sr(3)Li(2) crystallize with tetragonal unit cells (Sr(19)Li(44), I-42d, a = 15.9122(7) Å, c = 31.831(2) Å, Z = 4, V = 8059(2) Å(3); Sr(3)Li(2), P42/mnm, a = 9.803(1) Å, c = 8.784(2) Å, Z = 4, V = 844.2(2) Å(3)). The first compound is isostructural with the recently discovered Ba(19)Li(44). Sr in Sr(19)Li(44) can be fully replaced by Ba with no changes to the crystal structure, whereas the substitution of Sr by Ca is only possible within a limited concentration range. Sr(3)Li(2) can be assigned to the Al(2)Zr(3) structure type. The crystal structure determination of Sr(19)Li(44) was complicated by multiple twinning. As an experimental highlight, an electron microscopy investigation of the highly moisture- and electron-beam-sensitive crystals was performed, enabling high-resolution imaging of the defect structure.

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Section: Resultscontrasting

confidence: 52%

Section: ■ Introductionmentioning

confidence: 58%

Section: Introductionmentioning

confidence: 66%

Section: ■ Introductionmentioning

confidence: 99%

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Synthesis, Crystal Structure, and TEM Analysis of Sr₁₉Li₄₄ and Sr₃Li₂: A Reinvestigation of the Sr–Li Phase Diagram

et al. 2014

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“…To date, the dimer spectra of at least four different dyes have been derived utilizing certain critical assumptions. [3][4][5][6] In each case the reaction has followed the scheme 'Department of Pathology, New York University School of Medicine, New York, N. Y.…”

Section: Introductionmentioning

confidence: 99%