Abstract:The kinetics of substitution reactions of the CuODA and CuTDA binary complexes (ODA = oxydiacetate, TDA = thiodiacetate) with 1,10-phenanthroline (phen) and 2,2'-bipyridine (bipy) were studied in aqueous and DMSO solutions. These reactions were monitored spectrometrically using the stopped-flow method in the UV range. The studies were carried out at three temperatures-298.15, 303.15 and 308.15 K. The concentrations of the binary complexes were kept within the range of 0.2-0.5 mmol L −1 , whereas the concentrat… Show more
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