Methods of x-ray diffractometry are used to investigate the influence of plastic deformation on the state of the longrange order in alloys with the L1 2 , L1 2 (М), and L1 2 (MM) superstructure. It is demonstrated that the heterogeneous order-disorder phase transition accompanied by intensive accumulation of antiphase boundaries occurs under plastic deformation. The antiphase boundaries play an important role in the destruction of long-range order. Based on the available experimental results, a model of destruction of long-range order is constructed that takes into account the dislocation mechanisms of accumulation of antiphase boundaries under deformation.