The ionic liquid [Bmim][FeCl₄] catalyzes the formation of iron doped mesoporous silica aerogels for H₂O₂ decomposition

Organic–inorganic interactions revealed by Raman spectroscopy during reversible phase transitions in semiconducting [(C2H5)4N]FeCl4

“…A number of complexes with a tetrahedral tetrachloroferrate(III) anion [FeCl 4 ] À mixed with organic cation have been reported for their interesting catalytic properties. [15][16][17][18] For instance, the tetraethylammonium tetrachloroferrate ([(C 2 H 5 ) 4 N]FeCl 4 ) compound has already been used as photocatalyst for the oxidation of the cyclohexane 19 and the toluene 20 under visible light. This is a notable advantage over TiO 2 compound which requires ultraviolet (UV) irradiation to induce a photocatalytic oxidation of toluene.…”

Pseudohalogen Chemistry in Ionic Liquids with Non‐innocent Cations and Anions

“…Besides application in classic solid state chemistry, ILs can be used as reaction media to prepare (oligomeric) metal complexes, metal organic frameworks, coordination polymers [25–35] or cluster compounds incorporating main group elements [36–41] . Within SPP 1708, the synthesis of intermetallic cluster and nanoparticles, [3,42–56] the controlled synthesis of polyanions and cations, [57–61] solvent‐free chalcogenidometal‐containing materials, [62–75] deposition of nanocrystalline materials, [76–80] ionic liquids as precursors for inorganic materials, [81–83] ionic‐liquid‐modified hybrid materials, [84–87] as well as the low‐temperature synthesis of thermoelectric materials [88–92] were investigated. Moreover, theoretical [93–106] and solubility [107–114] aspects during the synthesis process were studied.…”