The interaction of 2-mercapto-benzothiazole with certain platinum group element derivatives

Wilson, Ray F.; Merchant, Philip

doi:10.1016/0022-1902(67)80459-7

Cited by 25 publications

(3 citation statements)

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“…The structures of its complexes with a few metal ions have also been investigated using various physical techniques (7)(8)(9). In our laboratory, we have for quite some time now been interested in the complexing properties of the HNCS group (10)(11)(12)(13).…”

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Complexes of 2-Mercaptobenzothiazole with Cu(II), Ni(II), Co(II), Cd(II), Zn(II), Pb(II), Ag(I), and Tl(I)

Khullar¹,

Agarwala²

1975

Can. J. Chem.

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Complexes of 2-Mercaptobenzothiazole with Cu(II), Ni(II), Co(II), Cd(II), Zn(II), Pb(II), Ag(I), and Tl(I)

Khullar¹,

Agarwala²

1975

Can. J. Chem.

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“…Mercapto-1,3-azole ligands have an important role in industry and medicine [4][5][6][7][8], and their coordination chemistry with transition metals attracted much attention [9][10][11][12][13][14][15].…”

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Mixed ligand palladium(II) and platinum(II) complexes of tertiary diphosphines and benz-1,3-imidazoline-2-thione, benz-1,3-oxazoline-2-thione or benz-1,3-thiazoline-2-thione

Al‐Jibori

Al-Zaubai

Mohammed

et al. 2007

Transition Met Chem

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Palladium(II) and platinum(II) complexes containing the mixed ligands tertiary diphosphines Ph 2 P(CH 2 ) n PPh 2 , (n = 1-4) and benz-1,3-imidazoline-2-thione, benz-1,3-oxazoline-2-thione or benz-1,3-thiazoline-2-thione have been prepared and characterized by elemental analysis, magnetic susceptibility, molar conductance and i.r. spectral data. 31 P-{ 1 H}-n.m.r. data have been applied to characterize the produced linkage isomers.

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“…Further, the compound is used as a precipitant for gravimetrie analysis of many metals [2]; it has found applications in the vulcanization of rubber [3] and as a corrosion inhibitor [4]. Several metal complexes of merBtz have been reported in the literature [5]. These complexes could form mixed ligand complexes with nitrogen-containing ligands [6].…”

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Lewis acidity of coordinatively unsaturated bis(2-mercaptobenzothiazolato)nickel(II) towards azoles and morpholine

Aly

Zidan

El‐Said

1991

Journal of Thermal Analysis

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The reactions of bis(2-mercaptobenzothiazolato)nickel(II) with some azoles and morpholine afforded the corresponding mixed ligand complexes. The studied azoles were 2-aminothiazole, benzothiazole, benzoxazole, 2-methylbenzoxazole and 2-mercapto-benzoxazole. The formation of new compounds was confirmed from the spectral data. The thermal decompositions of the compounds together with some related compounds reported in the literature, for comparison, were studied. The activation energies and other kinetic parameters were calculated from the Coats-Redfern and Horowitz-Metzger equations.2-Mercaptobenzothiazole(merBTz) exhibits biological activity in the sense that it can cause inhibition of tumour tissue [1]. Metal chelation is most probably involved in this effect. Further, the compound is used as a precipitant for gravimetrie analysis of many metals [2]; it has found applications in the vulcanization of rubber [3] and as a corrosion inhibitor [4]. Several metal complexes of merBtz have been reported in the literature [5]. These complexes could form mixed ligand complexes with nitrogen-containing ligands [6].Due to the above-mentioned particular importance of merBtz and because oxazole and thiazole derivatives are being used as analytical reagents in both industry and medicine [7,8], we embarked on a study of the interaction of Ni(merBtz)2 with a number of azoles and morpholine (morph).

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The interaction of 2-mercapto-benzothiazole with certain platinum group element derivatives

Cited by 25 publications

References 1 publication

Complexes of 2-Mercaptobenzothiazole with Cu(II), Ni(II), Co(II), Cd(II), Zn(II), Pb(II), Ag(I), and Tl(I)

Complexes of 2-Mercaptobenzothiazole with Cu(II), Ni(II), Co(II), Cd(II), Zn(II), Pb(II), Ag(I), and Tl(I)

Mixed ligand palladium(II) and platinum(II) complexes of tertiary diphosphines and benz-1,3-imidazoline-2-thione, benz-1,3-oxazoline-2-thione or benz-1,3-thiazoline-2-thione

Lewis acidity of coordinatively unsaturated bis(2-mercaptobenzothiazolato)nickel(II) towards azoles and morpholine

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