The influence of the type of halogen substituent and its position on the molecular conformation, intermolecular interactions and crystal packing for a series of 1-benzoyl-3-(halogenophenyl)thioureas
Abstract:By the reaction of benzoyl chloride, potassium isothiocyanate and the appropriate halogenoaniline, i.e. 2/3/4-(bromo/iodo)aniline, we have obtained five new 1-benzoyl-3-(halogenophenyl)thioureas, namely, 1-benzoyl-3-(2-bromophenyl)thiourea and 1-benzoyl-3-(3-bromophenyl)thiourea, C14H11BrN2OS, and 1-benzoyl-3-(2-iodophenyl)thiourea, 1-benzoyl-3-(3-iodophenyl)thiourea and 1-benzoyl-3-(4-iodophenyl)thiourea, C14H11IN2OS. Structural and conformational features of the compounds have been analyzed using X-ray diffr… Show more
“…29,30 In the organic solid-state, such considerations have attracted many systematic studies. [31][32][33][34][35][36][37][38][39][40][41][42][43][44] While these studies have largely focussed upon singlecomponent crystals, increasingly, attention has been directed to evaluating similar phenomena in multi-component crystals. [45][46][47][48][49][50][51] Not surprisingly, the majority of the aforementioned studies of both single-and multi-component crystals involve the interchange of halides.…”
The 1:1:1 binary co-crystal solvates formulated as 2,2'-dithiodibenzoic acid (DTBA), 4-halobenzoic acid (4-XBA) and dimethylformamide (DMF) for X = Cl (1), Br (2) and I (3) are isomorphous and the...
“…29,30 In the organic solid-state, such considerations have attracted many systematic studies. [31][32][33][34][35][36][37][38][39][40][41][42][43][44] While these studies have largely focussed upon singlecomponent crystals, increasingly, attention has been directed to evaluating similar phenomena in multi-component crystals. [45][46][47][48][49][50][51] Not surprisingly, the majority of the aforementioned studies of both single-and multi-component crystals involve the interchange of halides.…”
The 1:1:1 binary co-crystal solvates formulated as 2,2'-dithiodibenzoic acid (DTBA), 4-halobenzoic acid (4-XBA) and dimethylformamide (DMF) for X = Cl (1), Br (2) and I (3) are isomorphous and the...
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